MPT-AES法测定合金钢中的硅.pdfVIP

第24 卷，第 6 期 Vo 1. 24 , No.6 56 化学分析计量 CHEMICAL ANALYSIS AND METERAGE Nov.2015 2015 年 11 月 doi : 10.3969/j.issn.l008-6 145.2015.06.014 MPT-AES 法测定合金钢中的硅 高辉 l ，赵志添2 (1.抚顺特殊钢股份有限公司，辽宁抚顺 113001; 2 辽宁石油化工大学，辽宁抚顺 113001) 摘要 建立了微波等离子体炬原子发射光谱(MPT-AES) 测定合金钢中的硅含量的分析方法。考察了仪器最 佳实验条件、溶液酸度和钢中共存离子对测定的干扰，采用相似基体的标准钢样绘制工作曲线。硅的线性范围在 0.3-7.0μg/mL之间，检出限为 0.05μg/mL。测定结果的相对标准偏差为 1.2%-3.1 %(n=9) ，样品加标回收率在 97.0%-103.0% 之间，该法测定结果与国家标准方法测定结果相符合。 MPT-AES 法良好的精密度和准确度，可用于 测定合金钢中硅的含量。 关键词 MPT-AES; 硅;测定;合金钢 中图分类号: 0657.3 文献标识码:A 文章编号: 1008-6 145(2015)06-Ø056-Ø3 Determination of Silicon in AUoy Steel by MPT-AES I 2 Gao Hui , Zhao Zhitian (1. Fushun Special Steel Co.Ltd. , Fushun 113001 , China ; 2. Liaoning University ofPetroleum Chemical Technology , Fushun 113001 , China) Abstract The analysis method of microwave plasma torch-atomic emission spectrometry (MPT-AES) was established for the determination of silicon content in alloy steel. The best instrument working conditions. the e证民ts of solution acidity and the interference of coexistence ions in steel were inves创gated. The working curve was made by using the standard steel samples with similar matrix. The linear range of silicon was 0.3-7.0μg/ mL. and the detection limit of silicon was 0.05μg/ mL. The relative standard deviation of determination results was 1.2%-3 .1 %(n=9). the recovery of standard added sample was between 97.0%-103.0%. The determination results ofthe MPT-AES method were consi