N,N-二甲基甲酰胺-三氯甲烷-水体系液液相平衡数据的测定与关联.pdfVIP

NO.2 Vol.23 高校化学工程学报 第2H墨第 2 期 Joumal of Chemical Engineering of Chin四Universities Apr. 2009 2009 年 4 月 文章编号: 1∞3-9015(20ω)02-0 183-04 N，N-二甲基甲酿肢-三氯甲烧·水体系液液相平衡数据的现IJ 定与关联 叶长巢，林哉，邱挺 (福州大学化学化工学院，福建福州 350108) 摘 要g 为获得进一步研究DMF 废水萃取回收工艺所需的基础数据，利用液液平衡釜在常压下温度分别为30C、 35C、 40C时进行 N，N 二甲基甲酸肢，三氯甲统·水体系的液液相平衡实验，各物质的平衡组成由气相色谱分析，所得液液相 平衡数据用NRTL 和 UNIQUAC 模型进行关联，应用单纯形法求得相应的模型参数.计算值与实验值比较结果表明z NRTL 与 UNIQUAC 模型的计算值与实验数据吻合良好，模型计算的总平均绝对误差分别为 0.0032 和 0.0033 ，总平均 相对误差分别为 2.~也和 2.97%. 关键词: N，N 二甲基甲酸肢·三氯甲烧·水体系g 液液相平衡: NRTL 模型; UNIQUAC 模型 中图分类号z 创42.421 TQ031.1; TQ028 文献标识码:A Determination and Correlation of Liquid-Liquid Equilibrium Data for the Tema叮 System of DMF- CHCh- H20 YE Chang-she民 LIN Cheng, QIU Ting (College of Chemistry and Chemical Engineering, Fuzhou University, Fu血。u 350108, China) Abstracf: The study on liquid-liquid equilibrium (LLE) is important for N ,N -dimethylformamide (OM盯 reωvery 企Om wastewater by extraction. In order ωachieve the basic data for further sωdy， the LLE experiments of DMF-chloroform-water temary system at 30C, 35 C, 40 C and atmospheric pressure were carried out in an equilibrium cell. The equilibrium concentrations were determined by gas chromatogr叩hy. The NRTL and UNIQUAC models were adoptedω ∞πelate the Iiquid-Iiquid equilibrium data ofthe studied system, and 也e model par缸neters were estimated by the simplex method. The active coefficients in the LLE equations were ca1 culated by the NRTL and UNIQUAC models, and the calculated LLE data of OMF-chloroform-water temary system were ∞mpared with 由e experimental data Ba