生物膜电极反应器降解苯胺的研究.pdfVIP

笠云班等 生物膜咆极反应器降解苯肢的研究 生物膜电极反应器降解苯肢的研究势 笠云波l 许炉生附 关伟舅2 邵晓虹2 鲁丽君2 O. 浙tt工商大学环保设计研究院，浙江杭州 310014;2. 浙江工业大学生物与环境工程学院，浙扭杭州 310014) 摘要 使物膜咆极反应器是结合生物膜法和电催化技术而发展的新型废水处理技术.研究了生物膜电极上的苯胶降解，对 电流强度、温度、葡萄糖协同作用等因策的影响进行了观察。结果表明，生物膜电极反应糠簸高的电流强度为 5 mA.运行的最适温 度为 36 C，葡萄糖~H在胶的生物膜电极降解的协同作用在进水 COD 为 2000 mg/L 后达到章是大.色谱/1贡谱联用梭测笨胶降解中 间产物为 ψ援基-a-氨基戊酸国生物股也极上的苯胶降解在阴假发生，降解开环途径与常规降解途径不同. 关键词生物膜电极苯胶生化降解途径中间产物 Study 00 the degradation of aniline by biofilm electrode reactor Zhu Yu忡。1 .Xu Lusheng 2 • Wu Weiyong2 .Shao Xiao- hong 2 .Lu Lijun Z • (1. lnstitute 0/ Environmental Protection and Design ,Zhejiang Gongshang University. Hangzhou Zhejiang 310014;2. College 0/ Biological and Environmental Engineering. Zhejiang University of Technology. Hangzhou Zhejiang 310014) Abstract: Biofilm-electrode reactor was a new technology that enhanced pollutant degradation by electríc巾iocat­ alyst effect. Anílíne degradatíon by biofilrn吧lectrode was studied in this p且per. Effect of temperature , electric current. synergíc action of easy biodegradable substance on aníline bíofílrn-electrode degradatíon was observed. An íntermedí- ate product of 4-hydroxy幽旷amíno-pentatonic acid was found by mass spectrum detection. proved that ríng幽openíng re幽 action of aniline was índuced by cathode reduction. Base on whích , the new biodegradatíon pathway of aniline whích was different from internatíonalIy recognized bíodegradation pathway was found. The difference of two degradatíon pathway turned that the deoxídízing ambiance of cathode made key effect on it. Keywords: bíofìlm electrode; aniline; biodegradation pathway; intermediate product cmX 9.0 cmX 14.5 cm，置于超级恒温水浴槽(子501 生物膜电极反应器是结合生物膜法和电催化技 术而发展的新型废水处理技术。有研究者将脱氮菌 型)。将