载镧生物炭的优化制备及其对水体中砷的吸附.pdfVIP

中国环境科学 2015.35(8): 2433-2441 China Environmental Science 载搁生物炭的优化制备及其对水体中碑的眼附 冯彦房 12，薛利红 l ，杨 棋 1 ，孙海军 3，何世颖 1 ，杨林章 1 ，2 (1.江苏省农业科学院农业资源与环境研究所，农 业部长江下游平原农业环境重点实验室江苏南京 210014; 2. 中国科学院南京土壤研究所，土壤与农业可持续发展 国家重点实验室，江苏南京 210008; 3.南京林业大学现代分析测试中心，江苏南京 210037) 摘要:以玉米秸轩为原材料优化制备用于吸附水体中五价碑的载铜生物炭(La-bioch叫，对其表面进行了系统表征，同时考察了环境条件对 载铺生物炭吸附性能的影响.结果表明:相比负载前生物炭，负载后生物炭表面更粗糙，比表面积增大4.6 倍，同时表面成功负载有大量铜元素. 以获取对五价冽的最大吸附能力为目的，通过响应面模型获得 La-bi回har 的优化制备条件为:物料比咐La)l叫秸轩户9.47%，停留时间 =20min，热解温度=3ωoC.中性和酸性环境条件有利于 La-biochar 对柿酸根的吸附，而碱性条件则有不利影响;较高浓度的 C032 显著降低其 对硝酸根吸附，而同样浓度的 CI 和 F 不会造成明显影响. 关键词z 稀土榈:生物炭:吸附:五价耐:响应面法 中图分类号: X712 文献标识码:A 文章编号: 1000-6923(2015)08-2433-09 Optimized preparation of lantbanum uploaded biocbar and its application in adsorbing pentavalent arsenic ions l l 3 l from aqueous solu伽n. FENG Yan-fangl 气 XUE Li-hong , YANG Bei , SUN Hai-jun , HE Shi-ying , YANG Lin- l zhang ,2 (l .Key Laboratory of AgrlφEnvironment in Downstream of Yangtze Plain, Minis町of Agriculture , Institute of Resources and Environment, Jiangsu Academy of Agriculture Sciences,Nanjing 210014, China; 2.State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 , China; 3.Nanjing Forestry University, Analysis and Test Center, Nanjing 210037 , China). China Environmental Science, 2015 ,35(8): 2433-2441 Abstract: Lanthanum uploaded biochar (La-bioch叫 that utilized for removing pentavalent arsenic ions from aqueous solutions was prepared on the basis of com str百.w. The operation conditions during production procedure of La-biochar were optimized, and then La-biochar was characterized. Compared with control biochar (CK), the surface of La-biochar was rougher, and specific surface area incr，