催化光度法测定铬(Ⅵ)的研究.pdfVIP

第 31 卷第 6 期 工业水处理 Vol.31 No.6 2011 年 6 月 Industrial Water Treatment Jun. ,2011 E *fi !::j ~ì9!U 催化光度法测定锚(VI )的研究 崔英，张莉 (河南科技学院资源与环境学院，河南新乡 453003) [摘要]在 pH=5.0 的 NaAc-HAc缓冲介质中，铭(VI )能催化过氧化氢氧化菌素红的褪色反应。据此，建立了催 化光度法测定环境中痕量锚(VI )的新方法。在优化条件下，于最大吸收波长 422nm 处进行测定，铭(VI)浓度在 3.0x 5 7 10七1.0x 10- moVL 范围内呈现良好的线性关系;检lt1限为1.8xI0- moVL(3σ) ;对1.0x 10-6 moVL 的错(Vl)进行了平 行测定(n=l l) ，其相对标准偏差为 0.5%; 考察了多种共存离子的影响。将此法应用于废水中铅(VI )的测定，回收率 在 96.5%-97.7%之间，结果满意。 [关键词]催化光度法:锵(VI) ;过氧化氢 [中图分类号] 0657.39 [文献标识码] B [文章编号] 1 ∞5-829X(201l )06-∞78-02 Study on the determination of chromium (VI) by catalytic spectrophotomet叩 Cui Ying ,Zhang Li (College 0/Resource and Environme时， Henanl阳titute 0/Science and Technology ,Xinxiang 453003 ,China) Abstract: A new catalytic spectrophotometry method for the determination of trace chromium ( VI) has been deve- loped. The method is based on the significant catalytic action of trace chromium( VI) on the oxidation of bromophev- nol red by hydrogen peroxide in HAc-NaAc buffer solutions at pH is 5.0. Under the optimum conditions ,the deter- mination is carried out on the maximum absorptive wavelength 422 nm ,and when the chromium ( VI) concentration 7 s 7 is in the range of3.0xl0- - 1.0x lO- molJL, a veηgood linear relationship occurs. Detection limit is 1.8x lO- molJL. Parallel determination is carried out when the chromium (VI) concentration is 1.0x 10-6 molJL, its standard deviation is 0.5%. Many kinds of co-existing ions have been investigated. W