双波长紫外分光光度法测定渗滤液COD的研究.pdfVIP

第 3 卷第10 期 Vo l. 3. No. 10 低咣且程，营报 2009 年 10 月 Chinese Joumal of Environmental Engineering Oct . 2 0 0 9 双波长紫外分光光度法测定渗滤液 COD 的研究 张浩孙力平 (天津城市建设学院环境与市政工程系，天津 300384) 摘 要 针对重错酸拥法测定 COD 药剂耗费高、操作时间长、连续监测难、废液二次污染等问题，以垃圾渗滤液为例， 阐述了双波长紫外分光光度法预测污水 COD 的操作方法及其消除悬浮物千扰的原理。结果表明，在水样悬浮物波动较大 时，选取272 nm 及550 nm 的双波长预测模型较单波长预测模型和神经网络预测模型的预测结果更为准确。无需对水样进 行任何化学预处理，不需过膜，便可消除悬浮物对测定结果的干扰，是一种准确、便捷的 COD 测定方法。 关键词垃坡渗滤液紫外分光光度法双波长化学需氧量悬浮物测定 中图分类号 X703 文献标识码 A 文章编号 1673-9108(2009) 10-1755-04 Determination of leachate COD by double wavelenghs ultraviolet spectrophomety Zhang Hao Sun Liping ( Deparlment of Environmental and Municipal Engineering. Tianjin Institute of Urban Construction. Tianjin 300384. China) Abstract Many problems were found in COD determination by potassium dichromate oxidation , which is costly , time-consuming , hard continuous monitoring and secondary pollution produced , the new method and the disturbance elimination principal of suspended solid during landfill leachate COD determination were discussed. The results showed that the double wavelenghs forecast model , which 272 nm and 550 nm wavelength were choosen , was more exacted than single wavelength and nerve net forecast models when suspended solid concen- tration in sample fluctuate intensely. It was an exactly and convenient method of COD determination , which with- out any chemical pretreatment and mernbrane in suspended solid disturbance elirnination. Key words landfill leachate; ultraviolet spectrophornety; double wavelenghs; chernical oxygen dernand; suspended solid; determination