双酚A荧光性质及其测定研究.pdfVIP

第20 卷第 1 期 扬州职业大学学报 Vo l. 20 No.l 2016 年3 月 Jollmal of Yanl!;zhou Polytechnic Collel!;e Mar.2016 双酣 A 荧光性质及其测定研究 金根姊，惠苏平，茅 莹 (扬州职业大学，江苏扬州 225∞9) 摘 要:研究双盼A 的荧光特性，建立了用荧光光度法测定双盼A 的方法c 在 pH 为 5.0 缓冲溶液中，设 定最大激发波长 Ex =3∞nm ，最大发射波长 EM = 305nm ，测定不同浓度双盼 A 的荧光强度。结果表明，在 1. 235 X 10-5 -1. 235 X 1O- lO mol . L- 1 F= 浓度范围内，双盼 的浓度与荧光强度呈线性关系，线性方程为 A 8 6.234 +0. 1729C( 1O- mol. L-1) ，线性相关系数为 R =0. 995 0 用该方法对塑料样品中的双盼A 进行了测定， 取得较满意的结果。 关键词:双盼 A; 荧光光度法;测定 中图分类号:0657.3 文献标识码:A 文章编号:1 ∞8 -3693(2016)01 -ω48 -04 Research on Fluorescent Properties of Bisphenol A and Its Determination JIN Gen -di , HUI Su-ping , MA0 Ying ( Yangzhou Polytechnic College , Yangzhou 225009 , China) Abstract: In this article , the fluorescent properties of Bisphenol A were studied and determination of Bisphe- nol A was achieved via Fluorescence spectro-photometry. The fluorescence intensity of Bisphenol A of different concentration was measured at 300nm of the maximum excitation wavelength Ex and 305nm of the maximum e- mission wavelength Em in the buffer solution of pH 5. O. Results showed that the fluorescence intensity changed linearly with the concentration of Bisphenol A when the concentration ranged from 1. 235 x 10 -5 to 1. 235 x 10 -lO mol . L -1 , revealing the linear equation F = 6.234 + O. 1729C( 10 -smol • L -1) and 0.995 of the linear correlation coefficient R. The