V-PHZSM-5催化生物乙醇流化床脱水制乙烯的研究.pdfVIP

石油学报(石油加工〉 2008 年 10 月 ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION) 增刊 文章编号: 1001-8719(2008) 增刊-0234-03 V-PjHZSM-5 催化生物乙醇流化床脱水制乙烯的研究 洪爱珠，颜桂炀，刘欣萍，肖荔人，陈庆华 (福建师范大学化学与材料学院，福建省改性塑料技术开发基地，福建福州 350007) 摘要:以浸渍法制备的 V-P/HZSM-5 为催化剂，在自行设计的流化床反应装置上评价了其催化生物乙醇脱水制 乙烯的性能，考察了生物乙醇杂质对其使用寿命的影响，并探讨了催化剂的再生性能。结果表明， V-P/HZSM-5在反应原料流速 0.1 ml/ min、反应温度 220C 、催化剂用量 3 g 的条件下，可使乙醇转化率和乙烯 选择性均在 90% 以上，且该催化剂表现出良好的催化稳定性和再生性能。 关键词:生物乙醇p 乙烯g 流化床; V-P/HZSM-5 中图分类号: 0643.3 文献标识码:A STUDY ON ETHYLENE PREPARATION WITH BIOLOGY ETHANOL DEHYDRATION CATALYZED BY V-PjHZSM-5 IN FLUID BED HONG Ai-zhu. YAN Gui-yang. LIU Xin-ping. XIAO Li-ren. CHEN Qing-hua (College åf Chemistry and Materials Science. Fujian Normal University. Fujian 晶10dified Plastic Research Develop Technology Base. Fuzhou 350007. China) Abstract: The cata1ytic activity of V-P/HZSM-5 prepared by impregnation method was examined on bio10gy ethano1 dehydration to prepare ethy1ene in seJf-design fluid bed reactor. The influence of impurity in biology ethano1 to the use life of V-P/HZSM-5 was examined , and the regeneration of V-P/HZSM-5 was a1so discussed. The results showed that , under the conditions of O. 1 ml/min reaction material flow ve10city , 220C reaction temperature , 3 g .cata1yst , the ethano1 conversion and ethy1ene se1ectivity both can reach above 90% over V-P/HZSM-5 , with favorab1e cata1ytic stability and regeneration capability. Key words: bio10gyethanoh ethy1ene; fluid bed; V-P/HZSM-5 Along with the fast development of social biology energy sources technology and