三氯异氰尿酸在模拟水生态系统中归趋的研究.pdfVIP

第26卷 第4期 生 态 科 学 26(4)：36】一366 2007年8月 Ecological Science Aug． 2007 三氯异氰尿酸在模拟水生态系统中归趋的研究 周孝治 ，陈菊芳 ，聂湘平 ，江天久 1．暨南大学环境工程系，广州51 0632； 2．暨南大学水生生物研究所，广州 5lO632 【摘要】 利用高效液相色谱法对三氯异氰尿酸(TCCA)在微宇宙模拟水生态系统中的归趋，包括 TCCA在水体、沉积 物、生物体r皇冠草、河蚬、异育银鲫)等不同分配相及生物体不同组织中的分布、富集以及迁移等动态变化过程进行了 研究。结果表明：TCCA进入模拟水生态系统后，除发生水解外，其余或被水生生物所吸收，或者沉降进入底泥中。水 生生物对TCCA有不同程度的富集和残留。水草对TCCA的吸收较大，尤其是叶片部分；河蚬、鱼体对TCCA具有明 显的吸收积累，并且在体内的残留时间较长，不同组织对TCCA的吸收积累存在明显的差别，在内脏中的积累量比肌肉 组织高。不同生物对TCCA的分布和富集存在着较大的差异，其趋势为皇冠草河蚬异育银鲫。 关键词：微宇宙模拟水生态系统；三氯异氰尿酸；环境归趋；高效液相色谱 中图分类号：Q178 文献标识码：A 文章编号：1008．8873(2007)04．361—06 Dynamics and fate of TCCA in a simulated micro-cosmos system ZHOU Xiao．zhi ，CHEN Ju．fang” ， NIE Xiang-ping ，JIANG Tian-jiu J．Environmental Engineering Department ofJinan University,Guangzhou 510632,China； 2．Institute ofHydrobiology,Jinan University,Guangzhou 510632,China Abstract：Distribution，accumulation and transfer dynamics of TCCA in water，sediments，and biota in a simulated micro-cosmos system were studied by HPLC．The results showed that once TCCA was released into water body，some were hydrolyzed in aqueous solutions；some were assimilated by aquatic organisms or precipitated into sediments．There were differences in distribution，accumulation and transfer dynamics of TCCA among different aquatic organisms．Echinodorus amazonicus adsorbed TCCA mainly by its leaf instead of its roots and reached to an equilibrium quickly；Allogynogenetic crucian carp and Corbicula fluminea had obvious ability to accumulate TCCA，which could retain in these organisms for a long time．Significant differences of TCCA bioaccumulation existed between visceral and muscle．and higher concentration of TCCA was found in visceral tissues． It was found that bioaccumulations of TCCA varied with species．and the order was