化学镀纳米银阴极在聚合物LED中的应用.pdfVIP

SEMICONDUCTOR OPTOELECTRONICS Vo1．28 No．6 Dec2007 ． 化学镀纳米银阴极在聚合物LED中的应用 黎学明，易声伟，刘仁龙，谢昭明 (重庆大学 化学化I-学院，重庆 400044) 摘 要： 提出一种基于化学镀方法替代真空蒸发镀制备聚合物发光二极管(LED)阴极的思 路。采用Ag(NH。)2--一KNac H Os体系将纳米Ag沉积于MEH—PPV薄膜表面并形成ITO／ MEH—PPV／Ag发光二极管。用SEM和XRD表征化学镀银层结构与形态，通过椭偏仪研究 MEH—PPV浓度、体积等旋涂条件对其厚度影响的规律，初探发光二极管性能。结果表明，当 MEH—PPV浓度为5．5 mg·mL一，加入量 15肚I ，旋转 18 S(1 800 r／s)和 30 s(3 000 r／s)时，MEH— PPV厚度能控制在 1O0 nm左右；化学镀Ag层晶粒均匀致密，尺寸为30～40 nm，为典型面心立方 结构；驱动电压为6 V时，发光二极管能发出峰值波长为589 nm的桔红色光。 关键词： 聚[2一甲氧基一5一(2L乙基)己基对苯乙稀]；聚合物发光二极管；湿法制备；Ag电极 中图分类号：TN383．1 文献标识码：A 文章编号：1001—5868(2007)06—0812--03 Study on Polymer LED with Nanosize Silver Cathode by Electroless Plating Method LI Xue—ming，YI Sheng—wei，LIU Ren—long，XIE Zhao—ming (College of Chemistry and Chemical Engineering，Chongqing University，Chongqing 400044，CHN) Abstract： An electroless plating method is proposed for preparing the cathode of ITO／ MEH—PPV／Ag LED in order to overcome the limitation of vacuum evaporation deposition．The ITO／MEH—PPV／Ag LED was fabricated by plating silver to the surface of MEH—PPV layer on IT0 substrate in Ag(NH3) 一KNaC4 H iO6· 4H2O(Rochelle salt)solution，the thickness of MEH—PPV layer in different concentration and volume were analyzed by ellipsometer．Structure of silver film was characterized by SEM and XRD，the performance of LED was primarily evaluated．The result shows that thickness of MEH—PPV film iS 1O0 nm when the concentration and volume of MEH—PPV solution are 5．5 mg·mI 一 and 1 5“L，respectively，as well as spin time iS 18 s(1 800 rpm)and 30 s(3 000 rpm)．The electroless plating silver layer is very uniform， there is a typical structure of FCC