单分散球形硫化镉膜的电化学沉积.pdfVIP

第21卷 第6期 材 料 研 究 学 报 Vo1．21 No．6 2 0 0 7年12月 CHINESE J0URNAL 0F MATERIALS RESEARCH December 2 0 0 7 单分散球形硫化镉膜的电化学沉积 胡皓冰 汪 茫 陈 飞 陈红征 (浙江大学高分子科学与工程学系，硅材料国家重点实验室 杭州310027) 摘 要 提出一种在ITO玻璃上电化学沉积制备单分散近球形硫化镉粒子的新方法．在S—CdC12 DMSO电沉积体系中加入 少量的水制备出单分散膜层，调节沉积电流、电沉积时间或Cd 浓度可以改变膜层的粒子分布密度．结果表明，在电沉积的整个 IT0玻璃表面上均分布有硫化镉沉积，且不同厚度膜层上的沉积其 S与Cd的原子比不同．在电沉积硫化镉膜层上蒸镀铜酞菁 制备出P n异质结，其 特性表明，单分散近球形硫化镉膜层载流子的传输由带导电控制机制向跳跃导电控制机制转变． 关键词 无机非金属材料，硫化镉／球型，电沉积，异质结 分类号 O641 文章编号 1005—3093(2007)06．0604-05 Electrodeposition of single—layered films comprising spherical CdS particles HU Haobing WANG Mang CHEN Fei CHEN Hongzheng (Department of Polymer ScienceEngineering，State Key Lab o／Silicon Materials，Zhejiang University，Hangzhou 310027) Supported by National Nature Science Foundation of China NOS50520150165 and the Developing Program of Changjiang Scholar and Innovation Team from Education Department of China under Grant N0 IRT0651．Manuscript received Februaxy 5．2007；in revised form May 16．2007． Ib whom correspondence should be addressed，Tel：f0571187952557，E—mail：mwang@z ．．iU edu cn ． ABSTRACT A new eIectrodeDosition method was proposed to prepare single-layered俐ms comprising sphericaI CdS particles on IT0 glasses by adding a Iittle of water into S—CdCI2--DMSO system．The distribution density of sphericaI CdS particles COUId be controlled by Simply adiusting electric CUrrent density．deposition time and the concentration of cadmium ion．IT0 glass SUrfaces were whollY deposited with CdS and the atomic ratios of S to Cd were different due to difierent thicknesses of deposition Iayer． Copper phthaIocyanine fiIms were deposited through a thermaI evaporati