工作场所空气中四溴化碳吸收液采样气相色谱测定方法的研究.pdfVIP

中国卫生检验杂志2007年12月第17卷第12期 Chinese Journal of Health Laboratory Technology，Dec 2007；Vol 17 No 12 2129 【论著】 工作场所空气中四溴化碳吸收液采样气相色谱测定方法的研究 范衍琼 ，卢启冰‘，冯婉丽 ，李玉萍 ，林小葵 (1．广东省江门市职业病防治所，广东江门 529000；2．广东省江门市新会区疾病预防控制中心，广东江门 529100) [摘要] 目的：建立工作场所空气中四溴化碳吸收液采样气相色谱测定方法。方法：选用无水乙醇作吸收液采集空气中 四溴化碳，以毛细管气相色谱(ECD)测定。结果：空气中四溴化碳浓度在0～20 ms／m3(以采集3 L空气样品计，相当于 l0 ml无水乙醇吸收液采样管中四溴化碳溶液浓度0～6 m1)时，线性关系良好(r：0．9997，n=3)，回归方程Y： 35520．3X一2966．5；方法的检出限为0．086 IIll(进样 1 ，3倍噪声所相当的量)；最低检出浓度为0．29 ms／m3(以采 集3．0 L空气样品计)；相对标准偏差在0．4％一4．0％之间；采样效率92．7％；四溴化碳乙醇溶液封闭严密，4~C冰箱保存 6 d稳定。结论：本方法适用于工作场所空气中四溴化碳的浓度测定。 [关键词] 四溴化碳；工作场所空气；气相色谱法 [中图分类号] 0657．7 1 [文献标识码] A [文章编号] 1004—8685(2007)12—2129—03 Research on sampling and determining method by gas chromatography for carbon tetra— bromide in air of workplace Fan Yah—qiong ，Lu Qi—bing ，Feng Wan．1i ，Li Yu-ping ，Lin X／ao—ku／ (1．Jiangmen Occupational Disease Prevention and Control Institute，Jiangmen 529000，China；2．Xinhui Center for Disease Control and Prevention，Xinhui 529100，China) [Abstract] Objective：To establish an absorbing solution sampling and GC analytical method for carbon tetrabromide in the air ofworkplace．Methods：Carbon tetrabromide in the air ofworkplace Was absorbed by 10 ml Ethanal，then analyzed by GC(ECD)． Results：The liner regression formula Was Y=35520．3X一2966．5 between 0～20 ms／m3 of target concentration in the air(r： 0．9997)．，rhe detection limit Was 0．086 t~／,a1．，rhe relative standard deviation Was 0．4％～4．0％．，rhe sampling efficiency Was 92．7％．The tightly closed sampling could be stored for 6 day at 4℃ and iIs results still remained stable．Condusion：The method is compatible with concentration detection of carbon tetrabromide in the air of workplace． [Key words] Carbon tetrabromide；Workplace air；Gas chromatograp