纳米TiO2光催化氧化愈创木酚的降解机理.pdfVIP

第27卷第l2期 工业水处理 Vo1．27 No．12 2007年l2月 Industrial Water Treatment Dec．，2007 纳米TiO2光催化氧化愈创木酚的降解机理 王昶 ，陈文东 ，李兆光2，李桂菊1，贾青竹 (1．天津科技大学环境科学与工程系，天津 300457；2．天津化工研究设计院，天津 300131) [摘要]以木质素的模型物愈创木酚(G—M)为研究对象，采用自制的纳米TiO 作光催化剂，在一定的降解条件 下对G—M光催化降解的动力学和机理进行了研究。实验表明G—M的光催化降解过程包括吸附和降解两部分，通 过对G—M在Tio2表面吸附性能的测定，得到其吸附平衡常数，在此基础上运用L—H方程对G—M光催化降解的动 力学方程进行讨论，得到降解反应动力学方程 1／r=1．744／C+0．103 4。采用有机物特征功能团的显色法，对G—M光 催化降解反应过程的中间产物进行了分析，推断在G—M降解反应过程中出现了开环、脱羧，最终完全分解矿化生成 二氧化碳和水。 [关键词]废水处理；愈创木酚；光催化降解；反应动力学 [中图分类号]X703；TQ134．1 1 [文献标识码]A [文章编号]1005—829X(2007)12—0018一o4 The degradation mechanism of nano-TiO，photo—catalytic oxidation of methyl catechol Wang Chang ，Chen Wendong ，Li Zhaoguang2，Li Guiju ，Jia Qingzhu (1．Department ofEnvironmental Science and Technology，Tianjin University ofScience and Technology，Tianjin 300457，China；2．TianjinResearchDesignInstitute ofChemicalIndustry，Tianjin 300131，China) Abstract：The photo-catalytic degradation mechanism ofmethyl catechol(G-M)has been investigated by using TiO2 as an activated photo-catalyst prepared in the lab．It is indicated from the results that the G—M photo-catalytic degradation includes two processes：adsorption and degradation．The adsorption equilibrium constant and the kinetic equation for photo-catalytic degradation are obtained by measuring of the capability of adsorption of G—M on the surface ofTiO2，which is 1／r=1．744／C+0．103 4．Through the changes on the intermediates products with the organic character functional groups in the G—M degradation．it is found that the G—M appeared opening phenyl and taking off carboxyl，finally that is mineralized to CO2 and H20 in the reaction of TiO2． Key WOrds：wastewater treatment；methyl catechol；photo—catalytic degradation；reaction kinetics 目前国内造纸废