Ca0．80Zn0．20Te晶体的生长及性能研究.pdfVIP

第36卷 第6期 人 工 晶 体 学 报 Vo1．36 No．6 2007年 12月 JOURNAL OF SYNTHETIC CRYSTALS December，2007 Cdo．80 Zno．20 Te晶体的生长及性能研究 方 军，赵北君，朱世富，何知宇，高德友，张冬敏，程 曦，王智贤 (四川大学材料学院，成都610064) 摘要：用本实验室合成的cd。 zn。 Te多晶料为原料，采用改进的布里奇曼法在镀碳和未镀碳的石英安瓿中生长 出cd。 zn。 Te晶锭。使用x射线衍射仪对合成产物及晶锭进行了分析，生长晶体的x射线衍射峰尖锐，摇摆谱 对称，表明晶锭的结晶性能较好；用IRPrestige-21红外光谱仪分析了晶体的红外透射光谱，测试结果表明安瓿镀碳 后生长的晶体位错密度小，均匀性较好，电阻率优于未镀碳安瓿生长的晶体；晶体的蚀坑密度在1O 一10 cmI2之 间，比未镀碳安瓿生长的晶体低1个数量级。 关键词：碲锌镉；晶体生长；XRD；红外光谱；蚀坑密度 中图分类号：0782 文献标识码：A 文章编号：1000-985X(2007)06．1293-04 Study on the Crystal Growth and Properties of Cd0 Zn0 Te ． 80 ． 20 FANG Jun，ZHAO Beijun，ZHU Shi-fu，HE Zhi—yu，GAO De-you， ZHANG Dong—min，CHENG Xi，WANG Zhi-xian (Department of Materials Science，Sichuan University，Chen u 610064，China) (Received 23 J0nuary 2007) Abstract：Cdo Zno 20 Te ingots were grown in qua~z ampoule with and without carbon coating， ． 80 respectively，by modified Bridgman method using high purity Cdo Zn0 2 Te polycrystals as initial material ． 8 synthesized by our laboratory．The X-ray diffraction spectra showed that the integrality of the crystals was good．The infrared spectrum was obtained by Prestige-21 Fourier Transform Infrared Spectrometer．The result of infrared spectrum showed that the transmittance of the crystals grown in ampoule with carbon coating was better than those grown without carbon coating．The／-V curve showed that the former res