浅析四氯化钛精致尾渣的综合利用研究.doc

四氯化钛精致尾渣的综合利用研究 马娜1，陈丽杰2，瞿金为3，张洋3 （1.河南晋开化工投资控股集团有限责任公司，河南开封 475000； 2.江西理工大学 冶金与化学工程学院，江西赣州 341000； 3.中国科学院 过程工程研究所，北京 100190） 摘要：对攀钢钛业公司生成的四氯化钛精致尾渣进行碱浸，考察了浸出介质、反应温度、碱浓度、液固比、氧压和反应时间对钒浸出率的影响。在合适的工艺条件下，钒浸出率达95%以上。浸出液先沉淀铝，再分步结晶分离氯和钒。浸出液先蒸发结晶生成氯化钠，再冷却结晶制备出纯度89%以上的正钒酸钠。实现了铝、钠、氯和钒的高效分离与高附加值产品的转化，解决了四氯化钛精制尾渣堆放时的有价资源流失和环境污染问题。 关键词：四氯化钛；尾渣；碱浸；分离；结晶；正钒酸钠 中图分类号：X758 文献标志码：A 文章编号：1007-7545（2017）07-0000-00 Study on Comprehensive Utilization of Titanium Tetrachloride Refined Tailings MA Na1, CHEN Li-jie2, Qü Jin-wei3, ZHANG Yang3 （1. Henan Jinkai Chemical Investment Holding Group Co., Ltd, Kaifeng 475000, Henan, China; 2. School of Metallurgical and Chemical Engineering, Jiangxi University of Science Technology, Ganzhou 341000, Jiangxi, China; 3. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China） Abstract：Titanium tetrachloride refined tailings produced by Panzhihua Iron and Steel Company was leached with alkali. Effects of leaching medium, reaction temperature, alkali concentration, L/S, oxygen pressure, and reaction time on vanadium leaching rate were investigated. The results show that vanadium leaching rate is 95% above under optimum conditions. Lixivium firstly precipitated aluminum, and then chlorine and vanadium were separated by fractional crystallization. Leachate is evaporated to crystallize sodium chloride and then cooled to crystallize sodium vanadate product with purity of 89% above. Technical route of efficient separation of aluminum, sodium, chlorine, and vanadium, and conversion of high value-added products are realized. Valuable resource loss and environmental pollution existing in stacking of titanium tetrachloride refined tailings are addressed. Key words：titanium tetrachloride; tailings; alkali leaching; separation; crystallization; sodium vanadate 氯化法生产粗TiCl4时需要使用铝粉来脱除杂质钒在粗TiCl4生产过程中，渣中的五氧化二钒被氯化，最终生成了三氯氧钒向其中加入铝粉后，TiCl4与铝反应生成TiCl3，其中铝粉还原TiCl4生成的AlCl3起到催化作用。TiCl3与VOCl3发生反应生成VOCl2，因而达到脱除钒的目的生成的VOCl2与其它固体杂质以残渣分离出去，由于残渣中还有TiC