自蔓延冶金法合成LaB6微粉.pdfVIP

___________________________________________________________________________ 自蔓延冶金法合成LaB 微粉 6 张廷安, 豆志河 (东北大学 材料与冶金学院 沈阳 110004) 摘要：采用自蔓延冶金法制备出了LaB 微粉。对La O -B O -Mg 反应体系的相关反应进行了热力学和动力 6 2 3 2 3 学分析，确定了反应气氛以及相关的动力学参数。对热爆产物及浸出产物进行 X-ray 衍射、扫描电镜、透 射电镜分析和粒度分布测试仪等分析。结果表明：热爆产物由LaB ，MgO，少量 Mg B O 以及LaOCl 等 6 3 2 6 相组成，采用盐酸和硫酸两步浸出可以获得纯净的单 相的 LaB 。LaB 的纯度大于 99%，其平均粒径为 6 6 1.92 m ，计算得LaB6 的晶格常数a=0.4148nm 。 关键词：绝热温度; 差热分析；能谱分析；六硼化镧； 扫描电镜分析 中图分类号： O462 文献标识码： A Preparation and Characterization of LaB6 by SHS-Metallurgy ZHANG Ting-an, DOU Zhi-he (School of materials and metallurgy, Northeastern University, Shenyang 110004.) Abstract:LaB6 powder was prepared by Self-propagating High-temperature Synthesis Metallurgy (SHS Metallurgy). The relative reactions of B O -La O -Mg systems were analyzed thermodynamically and dynamically 2 3 2 3 and then the reaction atmosphere and the dynamical parameters were obtained. The combustion products and leached products were analyzed by X-ray 、SEM 、TEM and granularity analyzer. The results indicated that the combustion products consisted of LaB ，MgO，little Mg B O and LaOCl. The single phase LaB was obtained by 6 3 2 6 6 leaching first with HCl and then with H SO . LaB purity is shown not lower than 99% and its average particle