锑冶炼中砷碱渣与二氧化硫烟气综合回收清洁工艺探讨.pdfVIP

第24 卷第（3-4）期 Vol.24，No. （3-4） 2 0 1 0 年 10 月 Jiangxi Nonferrous Metals Oct . 2 0 1 0 文章编号：1005-2712 （2010）(3-4)-0097-04 锑冶炼中砷碱渣与二氧化硫烟气 综合回收清洁工艺探讨 单桃云， 刘鹊鸣， 谈应顺 （锡矿山闪星锑业有限责任公司，湖南 冷水江417500 ） 摘 要：通过将炼锑中产生的含砷碱渣经过浸出、含砷碱溶液吸收废气二氧化硫、硫化钠等硫化剂脱 砷、硫酸铁深度除砷以及净化浓缩干燥等过程后，难以处理的砷碱渣和废气低含量的二氧化硫得到 彻底处理 整个处理过程，锑回收率达到 ，砷开路率超过 ，二氧化硫吸收率超过 ，使烟气 . 99％ 90％ 95% 达到排放标准，碱转化为亚硫酸钠，达到了以废治废的目的，是一种清洁炼锑的工艺. 关键词：砷碱渣；二氧化硫烟气；综合回收；清洁工艺 中图分类号： 文献标识码： TF818 A Comprehensive Recovery of Clean Technology from Alrali Wastes and Suifur Dioxide in Antimony Smelting SHAN Tao-yun, LIU Que-ming, TAN Ying-shun （Hunan Hsikwangshan Twinking Star Co., Ltd., Lengshuijiang 417500 , China ） Abstract: Antimony smelting arsenic -alkali residue through leaching, absorption of alkaline solution containing arsenic with emissions of sulfur dioxide, sodium sulfide and other sulfide solvent for removing arsenic, and with ferric sulfate for the depth of the removal of arsenic, purification and concentration and drying process, arsenic- alkali residue of difficult to handle and low content of sulfur dioxide emissions are thorough treatment. The treatment in the whole process, recycling rate of antimony is 99%,and open circulation rate of arsenic is over 90%, sulfur dioxide by absorbing is more than 95%, the gas for emission reach the standard, and alkali transformed into Sodium Sulfite. Waste in Antimony smelting reached comprehensive treatment, and is a clean p