硅铬合金（Silicon chromium alloy）.docVIP

硅铬合金（Silicon chromium alloy） EDTA titration determination of aluminum 1 scope This standard provides for the determination of aluminum content by EDTA titration method, reagent material, instrument and equipment, analysis procedure and calculation of the results. This standard is applicable to the determination of aluminum alloy aluminum alloy, measuring range (quality score) : 0.30% - 2.50%. 2 method feeds Sample dissolved in nitric acid, hydrofluoric acid, make four fluoride silicon, silicon generated by perchloric acid smokes flooding the completely, chromium solution with ammonia extraction, again with sodium hydroxide to remove iron, then add the excessive EDTA, in the PH5 ~ 6 conditions, PAN as indicator, with copper sulfate excessive EDTA standard solution titration, adding sodium fluoride taking aluminum, release of EDTA with copper sulfate standard solution titration, the second time according to the consumption of copper sulfate, calculate the mass fraction of aluminum. Three reagents 3.1 ammonium nitrate (solid) 3.2 boric acid (solid) 3.3 nitric acid (rho 1.42 g/mL) 3.4 hydrofluoric acid (rho 1.15 g/mL) 3.5 perchloric acid (rho 1.67 g/mL) 3.6 ammonia (rho 0.90 g/mL) 3.7 hydrochloric acid solution (1 + 1) 3.8 sodium hydroxide solution (250g/L), stored in plastic bottles 3.9 fluoride sodium solution (50g/L), stored in plastic bottle. 3.10 buffer solution: to take 200g of ammonium acetate in 300mL beaker, add 10mL acetic acid (rho 1.05 g/mL), dissolve, dilute with water to 1000mL, and mix well. 3.11 ammonium nitrate lotion (10g/L) 3.12 phenolphthalein indicator (2g/L) is prepared using ethanol solution (3 + 2). 3.13 PAN indicator (1g/L) : ethanol preparation. 3.14 EDTA standard solution (0.01 molar) Copper sulfate standard solution (0.01 mol/L) 4 sample Q/SJFC. J08-011.4-2008 The specimen should be screened by 0.125 mm. 5. Analysis procedure 5.1 try shoes The 0.25 g test is said to be accurate to 0.0001 g. 5.2 blank test Do blank experiments with the test ma