碳的催化气化（The catalytic gasification of carbon）.docVIP

碳的催化气化（The catalytic gasification of carbon） The effect of cation and anion on gasification The catalytic effect of additives is related to the type of cationic ions, and the stronger the gold properties of cationic ions, the more obvious the catalytic effect on the carbon gasification reaction. Different carbonates have different effects on the speed of carbon gasification reaction, and several carbonates have a certain catalytic effect on the carbon gasification reaction, and the influence rule is K2CO3 Na2CO3 Li2CO3 BaCO3 CaCO3 MgCO3. The catalytic activity of fluoride also has a certain rule: KF NaF LiF CaF2. Different potassium salts have a catalytic effect on the carbon gasification reaction. For compound salt, the catalytic effect of the KNO3 is the best, followed by KOH, K2CO3, K2SO4, K2SiO3 and K3PO4. For the halogenated potassium, the effect of its effect on the rate of carbon gasification reaction is complicated. For sodium and lithium, the rule is similar to that of potash. The gasification speed of activated carbon is obviously faster than that of graphite, and the catalytic regularity of various salts is consistent with the catalytic rule of graphite. The effect of temperature on the catalytic reaction of carbon gasification In the case of carbon gasification catalysis, the temperature increase, the carbon catalyzed gas rate is greatly increased relative to the non-catalyst gasification reaction. At 800 ℃ gasification reaction rate at about 3% without catalyst, a catalyst of carbon vaporization rate at about 10%, and in 850 ℃ when no catalyst of carbon gasification reaction rate at about 6%, an increase of just 3%, a catalyst of carbon vaporization rate is as high as 70%, increased significantly. The effect of KCl on carbon gasification reaction at different temperatures is similar to that of sodium metasilicate. It can be seen that the catalytic effect of catalyst at high temperature is much stronger than that of low temperature. Catalytic m