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中国联塑 聚氯乙烯(PVC)知识(Chinese polyvinyl chloride (PVC) knowledge)
中国联塑 聚氯乙烯(PVC)知识(Chinese polyvinyl chloride (PVC) knowledge)
The biggest characteristic of PVC is flame retardant, so it is widely used in fire protection. But polyvinyl chloride releases hydrogen chloride and other toxic gases, such as dioxins, in the process.
The combustion of polyvinyl chloride is divided into two steps. In 240 ℃ to 340 ℃ before burning decomposition of hydrogen chloride gas and alkadiene contain a double bond, and then in 400-470 ℃ carbon burning.
Physical and chemical properties
Stable; Not susceptible to acid or alkali corrosion; Resistance to heat
PVC has a flame retardant (flame retardant value for more than 40), high chemical resistance (resistance to strong hydrochloric acid, sulfuric acid concentration is 90%, the concentration of 60% concentration of nitric acid and 20% sodium hydroxide), the advantages of good mechanical strength and electrical insulation. But its heat resistance is poorer, softening point is 80 ℃, 130 ℃ starts to break down discoloration, and precipitation of HCI.
Industrial polyvinyl chloride (PVC) resin are main crystalline structure, but also contains some crystal area (about 5%), so the PVC without apparent melting point, about 80 ℃ or so began to soften, heat distortion temperature (1.82 MPa) under load is 70-71 ℃, 150 ℃ under pressure to flow, and slowly began to release hydrogen chloride and the polyvinyl chloride (PVC) discoloration (change from yellow to red, brown, or black). The relative molecular weight of industrial polyvinyl chloride in the range of 4.8-48 million was 2-1.95 million. And the vast majority of industrial weighing all relative molecular mass of the resin in 10-200000, the number average molecular weight in 4.55 64000. Rigid polyvinyl chloride (without plasticizer) has a good mechanical strength, weather resistance and flame resistance, can be used as structural material, separately on the application in chemical pipes, sheet and injection molding products. Rigid polyvinyl chloride can be use
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