星型木质素衍生物增强大豆蛋白塑料 - 武汉理工大学学报.pdfVIP

28 5 武 汉 理 工 大 学 学 报 Vol. 28 No. 5 2006 5 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY May 2006 1 1, 2 1 1 1 魏 铭 , 黄 进 , 艾福金 , 樊李红 , 郑 化 ( 1. , 430070;2. , 510640) : 星型羟丙基木质素(HL)填充大豆蛋白(SPI) , 得到具有良好力学性能的可生物降解SPI/ HL 复 材料(SL) 复 材料的结构和性能被XRDDS SEMTEM 和拉力测试表征结果表明:仅仅加入质量分数 2% 的HL 就在大豆蛋白塑 料伸长率基本不变下,使拉伸强度达到 16. 8 MPa, 提高了2.3 倍随HL 含量的增加,HL 诱导形成纳米尺度的超分子特征 的微区虽然超分子微区使强度得到进一步提高, 但却导致甘油在SPI 基质中缺失, 材料变脆综 性能下降当HL 以单 分子形式存在于复 材料中时,伸展的支链能够将SPI 中的杂微区相互联系在 一起,得到最优力学性能的复 材料 : 大豆蛋白; 木质素; 共混; 增强; 超分子结构 : TQ 321 : A :2006 Soy Protein Plastics Strengt ened wit Starlike Lignin Derivatives 1 1, 2 1 1 1 WEI M ing , H UA N G Jin , A I Fuj in , FA N L ihong , ZH EN G H ua ( 1.School of hemical Engineering, Wuhan University of Technology, Wuhan 430070, hina; 2.State Key Laboratory of Pulp and Paper Engineering, South hina University of Technology, Guangzhou 510640, hina) Abstract: Biodegradable soy protein (SPI) plastics were compounded with starlike hydroxypropyl lignin ( HL) to produce SPI/ HL composite sheets w ith good mechanical performance. The structure and properties of composite materials were charac terized by Xray diffraction, differential scanning calorimetry, scanning electron microscopy, transmission electron microscopy and tensile test. It wasw orth noting that adding only 2% HL resulted in tensile strength of 16.8 MPa as much as 2. 3fold over that of pure SPI sheets without the elongation loss. As the HL content increased, HL can selfaggregate as supramolecular do main at nano scale, and the stronger int