原子吸收法测定土壤中铜和锌的不确定度评定.pdfVIP

安徽农业科学，Journal of Anhui Agri．Sci．2008,36(I4)：5964-5695 责任编辑 金琼琼 责任校对 卢瑶 原子吸收法测定土壤中铜和锌的不确定度评定 陈祥1，张晓艳 (1．重庆市园林绿化科学研究所，重庆400042；2．重庆市选旺食品有限公司，重庆401329) 摘要 f目的1评定原子吸收法测定土壤中铜和锌含量的不确定度。[方法]对原子吸收法测定土壤中铜和锌含量的取样量、体积(容器 和温度)、样品质量浓度、样品的质量含水量等不确定度分量进45-量化，计算出原子吸收法测定土壤中铜和锌含量的不确定度。[结果】 被测样品中铜含量为39．22m g，扩展不确定度 。)为5．1．4mg／kg，它是由标准不确定度(2．57mg／kg)乘以包含因子(2)得到的；被 测样品中锌含量为51．12mg／kg，扩展不确定度U( )为3．18mg／kg，它是由标准不确定度(1．59mg，l(g)乘以包含因子(2)得到的。[结 论1测定样品质量浓度引入的不确定度占较大比例，包括标准曲线和测定次数引入的不确定度，在测定中应给予足够重视。 关键词 原子吸收法；不确定度；土壤；铜；锌 中图分类号 S151．9+5 文献标识码 A 文章编号 0517-6611(2008)14—05964—02 Uncertainty Evaluation of．Determination on Copper and Zinc in Soil by Atomic Absorption Spectrometry CHEN Xiang et al(Chongqing Institute of Gardens Virescence Science，Chongqing 400042) Abstract [Objective]The study aimed to assess the uncertainty of copper and zinc content in soil by atomic absorption spectrometry．[Method] The uncertainty components such as the sampling quantity,volume(container and temperature)，mass concentration and mass water content of sample etc．in determining copper and zinc content in soil by atomic absorption spectrometry were quantified and the uncertainty of the Content of copper and zinc in soil was figured out by the same way，[Result]The copper content in detected samples was 39．22 mg／kg，its extend uncertainty (W。)was 5．14 mg／kg，which was got by that the standard uncertainty(2．57 mg／kg)mu!tiplied containing factor(2)．Similarly，the zinc content indetected sampleswaft51，t2mg／kg,its extend uncertainty WGu)Was 3．18mg／kg,whichwaS got bythatthe standardUncertainty(1．59mg／kg) multiplied contmning factor(2)．fConclusicnJ The uncertainty caused by mass concentration of sample had a large proportion in the determination, including the uncertainty caused by standard curve and measuring times，which should be paid more attentions during the measuration． Key words Atomic Absorp．tion Spectrometry；Uncertainty；Soil；Coppe