高贝利特硫铝酸盐水泥的熟料煅烧及其强度.pdfVIP

第27卷第3期 硅 酸 盐 通 报 V01．27 No．3 2008年6月 BULLETIN OF THE CHINESE CERAMIC SOCIETY June．2008 高贝利特硫铝酸盐水泥的熟料煅烧及其强度 要秉文，梅世刚，罗永会，吕臣敬 (石家庄铁道学院材料科学与工程分院，石家庄 050043) 摘要：用粉煤灰、石灰石、石膏作原料，烧制了以贝利特(卢-C S)为主、无水硫铝酸钙(C A，S)为辅的高贝利特硫铝酸 盐水泥，其 (p-C：S)达60％、 (C A，S)30％，熟料中无C，S和C，A。分析了率值和煅烧制度对熟料矿物形成的影 响，较佳的煅烧工艺参数是：碱度系数c 为0，95—1．03，铝硫比P为3．32—3．65，煅烧温度1280—1340℃，保温时 间45—70 min。试验表明C A，S使水泥具有较高的早期强度，大量的B-c2s持续水化保证了水泥强度的稳定增长。 水泥胶砂的1 d、3 d、7 d和28 d抗压强度分别为16．5 MPa、28．0 MPa、36．7 MPa和48．6 MPa。硬化水泥砂浆的总 孔隙率低，最可几孔径小。 关键词：高贝利特硫铝酸盐水泥；无水硫铝酸钙；贝利特；熟料煅烧；粉煤灰 中图分类号：TQ172．746 文献标识码：A 文章编号：1001-1625(2008)03-0601-05 Clinker Calcination and Compressive Strength of High Belite Sulphoaluminate Cement YAO Bing—wen，MEI Shi一 ng，LUO y0ng—hui LV Chen-jing (School of Materials Science and Engineering，Sh~iazhuang Railway Institute，Sh~iazhuang 050043，China) Abstract：The high belite sulphoaluminate cement(HBSAC)was made by calcined with fly ash， limestone and gypsum as raw materials．The primary and auxiliary mineral components of HBSAC are belite( 一C2S)and calcium sulphoaluminate(C4A3S)respectively．The main mineral constituents of the clinker are that 一C2S is over 60％ ，C4A3S is about 30％．There are not C3S and C3A in the clinker．The influence of clinker moduli values and calcined condition on the formation of clinker mineral was researched，and get the optimal calcined parameters from the experiment just as followings：alkalinity coefficient(C )0．95—1．03，alumina—sulfur ratio(P)3．32—3．65，calcined temperature 1280—1340℃， soaking time 45—70 min．The results shown that C4A3S can improve the early strength of HBSAC．The continual hydration of a great deal of 一C2 S leads to the in