CORROSION AND ELECTROCHEMICAL （腐蚀和电化学）.pdfVIP

Materials Science, Vol. 44, No. 6, 2008 CORROSION AND ELECTROCHEMICAL PROPERTIES OF BINARY COBALT AND NICKEL ALLOYS M. V. Ved’, T. O. Nenastina, V. V. Shtefan, T. M. Bairachna, and M. D. Sakhnenko UDC 621.35 The influence of pH of electrolyte on the tungsten content and current efficiency of a Co– W coating is determined. We determine the corrosion rates of Co – W and Ni– Pd alloys by the polarization resistance method and show that the coatings are classified as belonging to highly corrosion-resistant coatings. The catalytic reactivity of coatings in a model reaction of hydrogen release is assessed. Dependences of the corrosion resistance and catalytic reactivity of Co – W and Ni – Pd alloys on the contents of the components are obtained, and their character is jus- tified. Electroplates from alloys predominantly surpass metallurgical analogs in functional properties. This can be explained by the influence of synthesis conditions on the structure and morphology of the surfaces of materials. The electrochemical technologies enable one to control flexibly the content of alloy-forming components, their codeposition rate, and the state of the surface by varying both the compositions of electrolytes and regimes of polarization (from galvanostatic to pulse polarization or with current reverse). The electrochemical methods not only favor the realization of transitions between links of the interdependent chain process parame- ters–composition and structure of the material–properties–functions–use, but are also the base of monitoring and control of the development of transformations. Using such a method