掺铱黄金饰品的特征及检测方法.pdf

8 1 宝石和宝石学杂志 Vol. 8 No. 1 2006 3 Jour al of Gems a d Gemmology Mar. 2006 蓝 延, 赵曼曲, 陈 春 ( , 518026) : 采用显微镜和X 射线荧光光谱分析方法对掺 Ir 黄金饰品的外观 征掺入物的化学成分存在形式 等进行了研究研究表明, 掺入物主要为 Ir, Ru, Os 等, 它们以独立物相赋存于黄金饰品中掺入比例 w ( Ir+ Os) w ( Ru) 变化于65% ~ 70% 30% ~ 35% 之间掺入物的密度与足金的相近在黄金饰品中掺入Ir 等物质明显是掺杂行为, 导致黄金成色不足对掺 Ir 黄金饰品的检测方法进行了探讨 : 黄金饰品; Ir; 掺杂; X 射线荧光光谱分析 : P61928 : A : 1008214X( 2006) Characteristics of IridiumDoped Gold Jewelry and Its Determination LAN Ya , ZHA O Ma qu, CHEN Chu ( S henz hen L a bor at or y , N ati onal Cent re f or Quali ty S up e rv is ion and T est ing of Gem st one, Shenz hen 518026, Chi na) Abstract: T he superficial characteristics of iridiumdoped gold jew elry a d the occurre ce a d the chemical compositio s of doped material i gold jew elry have bee i vestigated by usi g op tical microscopy a d Xray fluoresce ce spectrum a alysis. T he results show that the doped materials are iridium, ruthe ium, osmium, etc, w hich occur i i depe de t phase. T he pro portio of w ( Ir+ Os) w ( Ru) is 65%~ 70% 30%~ 35% . T he de sities of the doped materi als are co siste t w ith that of gold. T he dopi g materials i gold jew elry result i the i suffi cie t purity. T he testi g metheds of iridiumdoped jew elry are probed. Key words: gold jew elry; iridium; dopi g; Xray fluoresce ce spectrum a alysis Ir , , , A u 1 ( Ir) ( Ru) ( Os) , Ir, Ru, Os A u Ir , , , , Au ! ∀ , Au , GIA , Au , X , ( Au , ,