batio3铁电陶瓷时效过程中的性能稳定性研究 study on property stability of batio3-based ferroelectric ceramics during ageing.pdfVIP

第26 卷 第3 期 电 子 元 件 与 材 料 Vol.26 No.3 2007 年3 月 ELECTRONIC COMPONENTS AND MATERIALS Mar. 2007 研 究 与 试 制 BaTiO3 铁电陶瓷时效过程中的性能稳定性研究 张 鸿，李志成 （中南大学材料科学与工程学院，湖南 长沙 410038） 摘要: 采用固相反应法制备了 La O 、Bi O 和 Ho O 掺杂的 BaTiO 基 PTC 热敏陶瓷元件，并对其时效特征进行 2 3 2 3 2 3 3 了研究。结果发现，一般样品的电阻率随时效时间的增加而变大，最大增量达58 %；但 Bi O 掺杂的样品出现时效反 2 3 常现象，即时效初始阶段样品的电阻率随时效时间增加而减小、减少率达 19.4 %，其后才逐渐增大。 关键词: 无机非金属材料；钛酸钡；固相反应法；时效特征；电性能 中图分类号: TN373 文献标识码:A 文章编号:1001-2028 （2007 ）03-0035-03 Study on property stability of BaTiO -based ferroelectric ceramics 3 during ageing ZHANG Hong, LI Zhi-cheng ( School of Materials Science Engineering, Central South University, Changsha 410083, China ) Abstract: La O , Bi O and Ho O doped BaTiO -based PTC ferroelectric ceramics were prepared by solid state reaction 2 3 2 3 2 3 3 method and their ageing characteristics were investigated. The results show that resistivities of the La O and Ho O doped 2 3 2 3 BaTiO3-based ferroelectric ceramics generally increased with the ageing time and the maximum increasing rate is 58 %. But Bi O -doped BaTiO -based ferroelectric ceramics show abnormal behaviors: with increase of ageing time, their resistivities of 2 3 3 samples decrease by 19.4 % in the ini