二甲苯对聚丙烯熔融接枝衣康酸的影响.pdfVIP

第22卷第2期 化工BI-T-U VoI．22，No．2 2008年2月 Chemical Indust~Times Feb．2．2008 二甲苯对聚丙烯熔融接枝衣康酸的影响 孟宪奎 崔青云 刘喜军 (齐齐哈尔大学化学与化学工程学院，黑龙江 齐齐哈尔 161006) 摘 要 通过熔融接枝技术采用反应型双螺杆挤出机制备了可反应性相容剂聚丙烯接枝衣康酸(PP—g—ITA)，研究 了二甲苯(DMB)对接枝物性能的影响。采用热重分析(TG)和傅立叶变换红外光谱(FIIR)对接枝物结构进行了分析； 采用非水滴定法对接枝物的接枝率(GR)进行了测定。结果表明：ITA已经接枝到PP大分子链上，ITA的引入导致接 枝物熔点( )和热分解温度( )略有改变；DMB对 GR影响较大，其作用类似于苯乙烯(st)，但却不参与反应。当PP／ ITA／DMB／DCP=100／8／10／0．8时，GR高达1．63％。 关键词 熔融接枝 可反应性相容剂 二甲苯 衣康酸 Effects of Xylene on the Melt Grafting of Polypropylene by Itaconic Acid Meng Xiankui Cui Qingyun Liu Xijun (College of Chemist~and Chemical Engineering，Qiqihar University，Heilongjiang Qiqihar 161006) Abstract The reactive compatilizer PP—g—ITA was prepared by melt grafting technique through reactive twin SCrew extruder and the effects of xylene(DMB)on the properties of the graft copolymer were studied．The structure of the grat copolymer was characterized by Thermometric Analysis(TGA)and Fourier Transform Infrared Spectrophotometer(gl一IR)． The grafting rmio(GR)was measured by the nonaqueous acid—base titration method．The results indicated that ITA was grafted on the macmmolecular chains of the polypropylene，and the melting point(Tm)of the graft copolymer and the thermal degradation temperature(Td)changed slightly attributed to the introduction of ITA．The effects of DMB，permorming as St，on GR of the graft copolymer were significant．but it did not take part in the reaction．Th e GR value was 1．63％ when the mass ratio of PP／rIIA／DMB／DCP Was 10o／8／10／0．8． Keywords melt grafting reactive compatilizer xylene ITA 聚丙烯(PP)是当今最重要的通用塑料之一。它 涂料、玻璃、金属、碳纤维等材料能更好地粘结在一 具有成本低、耐油及耐化学品优良、易加工、吸水吸湿 起。利用反应性挤出方法进行的熔融接枝具有设备 低、化学稳定性良好等优点，并以其产量大、应用面广 投资少、工艺