effect of oxide nanoparticles on thermal and mechanical properties of electrospun separators for lithium-ion batteries氧化物纳米颗粒对热量和机械性能的影响实际上电纺分隔符的锂离子电池.pdfVIP
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effect of oxide nanoparticles on thermal and mechanical properties of electrospun separators for lithium-ion batteries氧化物纳米颗粒对热量和机械性能的影响实际上电纺分隔符的锂离子电池
Hindawi Publishing Corporation
Journal of Nanomaterials
Volume 2012, Article ID 216012, 8 pages
doi:10.1155/2012/216012
Research Article
Effect of Oxide Nanoparticles on Thermal and Mechanical
Properties of Electrospun Separators for Lithium-Ion Batteries
Marco Zaccaria,1 Chiara Gualandi,2 Davide Fabiani,1
Maria Letizia Focarete,2 and Fausto Croce3
1 Electrical Engineering Department, Alma Mater Studiorum-University of Bologna, Viale Risorgimento 2, 40136 Bologna, Italy
2 Chemistry Department and National Consortium of Materials Science and Technology (INSTM, RU Bologna),
Alma Mater Studiorum-University of Bologna, Via Selmi 2, 40126 Bologna, Italy
3 Dipartimento di Scienze del Farmaco, Universita “G. d’Annunzio”, Via dei Vestini 31, 66100 Chieti, Italy
´
Correspondence should be addressed to Marco Zaccaria, marco.zaccaria@unibo.it
Received 23 July 2012; Revised 20 September 2012; Accepted 1 October 2012
Academic Editor: Russell E. Gorga
Copyright © 2012 Marco Zaccaria et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
This study reports the fabrication and characterization of poly(ethylene oxide) (PEO) and poly(vinylidenefluoride-co-
chlorotrifluoroethylene) (PVDF-CTFE) nanofibrous separators for lithium-ion batteries loaded with different amounts of fumed-
silica and tin oxide nanoparticles. Membrane morphological characterization (SEM, TEM) showed the presence of good-quality
nanofibres containing nanoparticles. Thermal degradation and membrane mechanical properties were also investigated, and a
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