原创力文档binding studies of a new water-soluble iron(iii) schiff base complex to dna using multispectroscopic methods绑定的研究一个新的水溶性铁(iii)席夫碱复杂使用multispectroscopic dna的方法.pdfVIP
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binding studies of a new water-soluble iron(iii) schiff base complex to dna using multispectroscopic methods绑定的研究一个新的水溶性铁(iii)席夫碱复杂使用multispectroscopic dna的方法
Hindawi Publishing Corporation
Bioinorganic Chemistry and Applications
Volume 2012, Article ID 126451, 9 pages
doi:10.1155/2012/126451
Research Article
Binding Studies of a New Water-Soluble Iron(III) Schiff Base
Complex to DNA Using Multispectroscopic Methods
Nahid Shahabadi, Zeinab Ghasemian, and Saba Hadidi
Department of Inorganic Chemistry, Faculty of Chemistry, Razi University, Kermanshah 74155, Iran
Correspondence should be addressed to Nahid Shahabadi, nahidshahabadi@
Received 4 April 2012; Accepted 11 June 2012
Academic Editor: Giovanni Natile
Copyright © 2012 Nahid Shahabadi et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
A novel iron(III) complex [Fe(SF)](ClO ) .2H O; in which SF = N,N -bis{5-[(triphenylphosphonium chloride)-methyl] salicyli-
4 3 2 0
dene }-o-phenylenediamine) has been synthesized and characterized using different physicochemical methods. The binding of
this complex with calf thymus (CT) DNA was investigated by circular dichroism, absorption studies, emission spectroscopy,
voltammetric studies, and viscosity measurements. The results showed that this complex can bind to DNA via external and groove
binding modes.
1. Introduction have been the subjects of intense investigation in relation
to the development of new reagents for biotechnology and
Schiff bases, characterized by the azomethine group (–RC= medicine [24–30]. To understand
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