原创力文档effect of ba2+ in bnt ceramics on dielectric and conductivity properties菲律宾媒体的影响+ bnt陶瓷介质和导电率属性.pdfVIP
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effectofba2inbntceramicsondielectricandconductivityproperties菲律宾媒体的影响bnt陶瓷介质和导电率属性
Vol.2, No.4, 357-367 (2010) Natural Science
/10.4236/ns.2010.24043
Effect of Ba2+ in BNT ceramics on dielectric and
conductivity properties
Konapala Sambasiva Rao, Kuan China Varada Rajulu, Bollepalli Tilak, Anem Swathi
Centre for Piezoelectric Transducer Materials, Department of Physics, Andhra University, Visakhapatnam, India;
sambasivaraokonapala@yahoo.co.in; konapala@
Received 11 December 2009; revised 13 January 2010; accepted 19 February 2010.
ABSTRACT luated; the difference in activation energies
could be due to the grain boundary effect. The
The polycrystalline (Na Bi ) Ba TiO (x = 0.026,
0.5 0.5 1-x x 3 activation enthalpy energies, have been esti-
0.055 0.065) (BNBT) ceramics have been mated and found to be Hm = 0.37 eV, 0.26 eV and
synthesized by conventional solid state sinter- 0.25 eV for BNBT-26, BNBT-55 and BNBT-65 re-
ing technique. The tolerance (t) factor of the spectively.
BNBT composition have been estimated and
found to be 0.988, 0.990 and 0.991 for x = 0.026, Keywords: MPB; Dielectric; Perovskite;
0.055 and 0.065 respectively, revealing system Conductivity; Tolerance Factor
is stable perovskite type structure. The com-
pound has a rhombohedral-tetragonal Morphtropic
Phase Boun- dary (MPB) at x = 0.065. XRD re- 1. INTRODUCTION
sults indicated the crystalline structure of the
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