2-巯基苯并噻唑对铜缓蚀行为的表面增强红外光谱研究.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) December Acfa Phys. -Chim. Sin. 2013 ,29 (1 2) ,2565-2572 2565 [Article] doi: 10.3866IPKU.WHXB201310294 2-蔬基苯并口塞瞠对铜缓蚀行为的表面增强红外光谱研究 霍胜娟. 方建慧 祝卿 陈利红 (上海大学理学院化学系，上海 200444) 摘要: 2-琉基苯并噬瞠(MBT)是Cu 的高效缓蚀剂，但是缓蚀机理存在较大争议.本文通过电化学极化曲线从 宏观角度对缓蚀效率进行评估，并利用原位衰减全反射·表面增强红外光谱技术结合理论计算研究了电位控制 下的微观吸附构型.结果表明:在较高电位(大于OV，相对饱和甘*电极(SCE))下， MBT和金属Cu 之间发生电 子转移， MBT 以硫醇式的环外S 和N 与金属Cu(l)离子配位在表面形成聚合物膜;在较低电位(小于o V, vs SCE)下， MBT通过环外S 原子以硫醇离子形式在金属Cu 表面直立吸附.表面膜阻止了腐蚀介质的侵蚀，起到 了较好的缓蚀效果. 关键词: 表面增强红外光谱; 衰减全反射， 2-统基苯并哇哇; 铜; 缓蚀机理 中图分类号: 0646; 0647 Suñace-Enhanced Infrared Absorption Spectroscopy Study of Anticorrosion Behavior of 2-Mercaptobenzothiazole on Copper HUO Sheng-Juan CHEN Li-Hong ZHU Qing FANG Jian-Hui (Department 01 Chemistry, College 01Sciences, Shanghai Universi纱~ Shanghai 200444, P. R. China) Abstract: 2-Mercaptobenzothiazole (MBT) is a highly efficient inhibitor of Cu. However, the inhibition mechanism is still unclear. In this paper, the anticorrosive e仔ect of MBT on a Cu surface at the macroscopic level was evaluated using a polarization curve technique. The potential-dependent adsorption geometries of MBT at the molecular level were investigated using electrochemical surface-enhanced infrared reflection absorption spectros∞py in attenuated total reflection mOde, together with theoretical calculations. The results indicated that the MBT molecules were adsorbed on the Cu surface vertically, in