原创力文档removal of organic matter from paper mill effluent by electrochemical oxidation删除从造纸厂废水有机物电化学氧化.pdf
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removal of organic matter from paper mill effluent by electrochemical oxidation删除从造纸厂废水有机物电化学氧化
Journal of Water Resource and Protection, 2011, 3, 32-40
doi:10.4236/jwarp.2011.31004 Published Online January 2011 (/journal/jwarp)
Removal of Organic Matter from Paper Mill Effluent by
Electrochemical Oxidation
1,2 1 3
Teresa Zayas , Mario Picazo , Leonardo Salgado
1
Posgrado en Ciencias Ambientales y
2Centro de Química del Instituto de Ciencias,
Benemérita Universidad Autónoma de Puebla, Puebla, México
3Depto. de Química, Universidad Autónoma Metropolitana Iztapalapa,
México D.F., MEXICO
E-mail : tzayasp@
Received October 25, 2010; revised November 29, 2010; accepted December 31, 2010
Abstract
The electrochemical oxidation of paper mill wastewater was studied using a dimensionally stable anode of
composition Ti/RuPb(40%)Ox. The oxidation process was analyzed as a function of electrolysis time and
with respect to the cell potential difference, electrolyte (NaCl) concentration, and pH of the sample. The pu-
rification of the effluent was evaluated through measurements of the removal of chemical oxygen demand
(COD), color, and total polyphenols, and using UV-Vis spectroscopy. The results showed that the presence
of NaCl is a determining factor in the purification process. Electrolysis of wastewater containing 5 g/L NaCl
at a cell potential difference of 6 V for 120 min, removed 99% of COD and the percent removal values of
color and polyphenols were 95% after 15 min of electrolysis. The UV-Vis spectrum showed evidence of th
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