合成与光催化性能.PDF

维普资讯 第 54卷 第 9期 化 工 学 报 V0l1．54 N09 2003年 9月 Journal 0f Chemical Industry and En ne ng (China) September 2003 超 临界 乙醇流体制备 TiO2光催化剂 (I) 合成与光催化性能 黄 彪 (福建农林大学材料工程学院，福建 南平 353001) 关键词 甲醛 超临界乙醇 Ti 光催化活性 中圈分类号 TQ031．2 文献标识码 A 文章编号 0438—1157 (2003)09—1315—40 PREPARATION OF PHOTO-CATALⅧ C TiO2BY SUPERCRITICALETHANOL 【I) SYNTHESIS AND PHOTOCATAIYSIS m A『NG Biao (SchoolofMaterialEngineering，FujianAgricultureandForestryUniversity，Nanping353001，Fujian，China) Abstract Photo-catalyticTi02waspreparedfrom tetraisopropyltitanate(唧 )insupercritiaclethano1．ItWas foundthat唧 insupercriticalethnaolcouldbeeffectivelyocnvertedintothe~rmtase—form ofTiO2crystallites． Theanatase-ofrm ofTiO2aSaphoto-actalystWas evaluatedforitsadsorptivityna dsubsequentphoto-actalytic activitiesonformaldehyde，oneoftheharmfulairpollutnatsintheenvironment．Asaresult，thesupercritiaclly treatde Ti02hadahighdecomtx~ing ability．Underthesameocndition，theexperimentWas repeated ofr5 times，na dphotocatalysisofthesamples didnotdcerease．ThisindiactedthatthesupercriticaltreatmentWas effcetivetopreparephoto-actalyticTiOz，whichWas featurebystability，longevitynadhighphoto—actalytic decompositionofformaldehydeforenvironmental cleaning．Meanwhile，unlikeocnventionalchemicalraection， which isocmplexna dtime-ocnsuming ，supercritiacltraetmentiseasytooperate，saving bothtimenadlabo r． Keywords formaldehyde，supercriticalethanol，Ti％ ，photo-actalyticactivity 面性质等)对光催化活性有较大影响[3--5]．目前大 引 言 多数研究中主要采用商品TiOz或将其改性后