NVP-丙烯酸共聚物水凝胶的制备与性能研究.docVIP

NVP/丙烯酸共聚物水凝胶的制备与性能研究 摘要：以N-乙烯基吡咯烷酮(NVP)、丙烯酸(AA)为原料，N,Nacute;-亚甲基双丙烯酰胺为交联剂，过硫酸钾(K2S2O8)为引发剂，采用自由基聚合合成水凝胶。分别研究了原料配比、交联剂用量、引发剂比例、盐浓度、pH对水凝胶吸水能力的影响，确定了最佳用量及条件。结果表明：NVP/丙烯酸共聚物水凝胶的最佳条件为丙烯酸跟NVP的质量比为1：1.1~1：1.2之间;引发剂的用量为丙烯酸单体质量的4%~5%;交联剂的用量为丙烯酸单体质量的7%~8%.水凝胶的吸水率随着盐浓度的增加而减小；pH为7~9时水凝胶的吸水率最高，合成温度是75℃。10426 关键词: N-乙烯基吡咯烷酮；丙烯酸；水凝胶；溶胀率；吸水率 Synthesis and Characterization of Copolymer Hydrogels of Poly(N NVP-co-acrylic acid) Abstract: Using acrylic acid(AA)and N-vinyl pyrrolidone(NVP) as starting materials, N-N#39;-methylene bisacrylamide as the crosslinker and potassium persulfate as the initiator, copolymer hydrogels of poly(N-vinyl pyrrolidone-co-acrylic acid) was synthesized by free-radical-initiated polymerization. Investigated the ratio of raw materials, crosslinker, initiator, salt concentration, pH on the absorption capacity of the hydrogel to determine the optimal dosage and conditions. The results showed that the optimum conditions of the synthesis of the hydrogel for AA with NVP mass ratio between 1:1.1~1:1.2; the dosage of initiator is the quality of acrylic monomer 4%~5%;the amount of crosslinking agent is the quality of acrylic monomer 7%~8%,and with the increasing salt concentration,the water-absorption rate of the hydrogel decreases;when the pH is between7~9 and the synthesis temperature is75 ℃,the water absorption of the hydrogel is highest. Key Words: Nndash;vinyl pyrrolidone; Acrylicacid; Nndash;Nrsquo; ndash;methylenendash;bisndash;acrylamide; Swelling rate; Water-absorption rate 目录 摘要1 本文以N-乙烯基吡咯烷酮(NVP)为主要原料, 选择丙烯酸为共聚单体,以N ,Nacute;-亚甲基双丙烯酰胺为交联剂，过硫酸钾(K2S2O8)为引发剂，采用自由基聚合合成了NVP丙烯酸共聚物水凝胶。然后再对NVP/丙烯酸共聚物水凝胶进行性能的测定与分析，探究单体配比、引发剂的用量、交联剂的用量、盐浓度、以及pH对水凝胶吸水性能的影响。 1实验部分 1.1实验仪器与试剂 1.1.1 实验仪器 傅立叶变换红外光谱仪（美国Thermo Nicolet公司的Nicolet 5700），电热鼓风干燥箱(1109531A)，DF-101S集热式恒温加热磁力搅拌器（巩义市予华仪器有限责任公司），HH-S型恒温水浴锅(江苏省金坛市医疗仪器厂)；GOCOC型玻璃仪器气流烘干器（巩义市英峪华高科仪器厂）；AL204电子天平（梅特勒-托利多仪器上海有限公司)；磁子，试管，烧杯，镊子；药匙；玻璃棒；洗耳球；移液管(10ml)；滤纸。 1.1.2 试剂 N-乙烯基吡咯烷酮(NVP)（分析纯AR,天津市光复精细化工研究所）, 反应前经减压蒸馏除去阻聚剂, 收