silver(i) complexes of imidazolidine-2-thione and triphenylphosphines solid-state, solution nmr and antimicrobial activity studies银(i)复合物imidazolidine-2-thione和三苯基膦固态核磁共振和抗菌活性研究的解决方案.pdfVIP

Spectroscopy 21 (2007) 61–67 61 IOS Press Silver(I) complexes of imidazolidine-2-thione and triphenylphosphines: Solid-state, solution NMR and antimicrobial activity studies Norah O. Al-Zamil a , Khulood A. Al-Sadhan a , Anvarhusein A. Isab b,∗, Mohamed I.M. Wazeer b and Abdul Rehman A. Al-Arfaj b a Department of Chemistry, Girls’ College Dammam, Saudi Arabia b Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia Abstract. Mixed ligand complexes of Ag(I) with triphenylphosphine (PPh ), triphenylphosphine sulfide (SPPh ), triph- 3 3 enylphosphine selenide (SePPh3) and Imidazolidine-2-thione (Imt) have been prepared. The solution as well as solid state NMR studies have been carried out to characterize these complexes. Both solid and solution NMR show the coordination via thione group on one side and (S/Se) or PPh on the other side. A higher antimicrobial activity is shown by [ImtAgPPh ]Cl 3 3 complex against gram negative Pseudomonas aeruginosa (P. aeruginosa) and Escherichia coli (E. coli) compared to the other two complexes i.e. [ImtAgSPPh ]Cl and [ImtAgSePPh ]Cl. 3 3 Keywords: Silver(I) complexes, imidazolidine-2-thione, triphenylphosphines, CP MAS NMR, antimicrobial activity 1. Introduction The complexation capacity of thiourea derivatives is well known [1–4] and the biological activities of thiourea complexes have been studied for different biological systems [5]. In recent years, the antifungal activity of thioureas and substituted thioureas and their Ni(II), Cu(II), Pt(II) and Co