synthesis and application of new ruthenium complexes containing β-diketonato ligands as sensitizers for nanocrystalline tio2 solar cells新的包含β-diketonato钌配合物配体的合成和应用作为纳米晶体的增敏剂二氧化钛太阳能电池.pdfVIP

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2011, Article ID 204639, 8 pages doi:10.1155/2011/204639 Research Article Synthesis and Application of New Ruthenium Complexes Containing β-Diketonato Ligands as Sensitizers for Nanocrystalline TiO2 Solar Cells Ashraful Islam,1, 2, 3 Surya Prakash Singh,1, 2 and Liyuan Han1, 2 1 International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan 2 Advanced Photovoltaics Center, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan 3 Center of Excellence for Research in Engineering Materials (CEREM), College of Engineering, King Saud University, Riyadh 11421, Saudi Arabia Correspondence should be addressed to Ashraful Islam, islam.ashraful@nims.go.jp Received 30 March 2011; Accepted 4 May 2011 Academic Editor: Mohamed Sabry Abdel-Mottaleb Copyright © 2011 Ashraful Islam et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Five heteroleptic ruthenium complexes having different β -diketonato ligands, [Ru(tctpy)(dppd)(NCS)] (1), [Ru(tctpy)(pd)(NCS)] ” (2), [Ru(tctpy)(tdd)(NCS)] (3), [Ru(tctpy)(mepd)(NCS)] (4), and [Ru(tctpy)(tmhd)(NCS)] (5), where tctpy = 4,4 ,4 -tricarboxy- 2,2 :6 ,2 -terpyridine, pd = pentane-2,4-dione, mepd = 3-methylpentane-2,4-dione, tmhd = 2,2,6,6-tetramethylheptane-3,5- dione, tdd = tridecane-6,8-dione, and dppd = 1,3-diphenylpropan