the effect of multidentate biopolymer based on polyacrylamide grafted onto kappa-carrageenan on the spectrofluorometric properties of water-soluble cds quantum dots基于聚丙烯酰胺接枝上的影响多齿的生物高聚物kappa-carrageenan spectrofluorometric水溶性cds量子点的性质.pdfVIP

Hindawi Publishing Corporation International Journal of Spectroscopy Volume 2011, Article ID 954252, 6 pages doi:10.1155/2011/954252 Research Article The Effect of Multidentate Biopolymer Based on Polyacrylamide Grafted onto Kappa-Carrageenan on the Spectrofluorometric Properties of Water-Soluble CdS Quantum Dots Ghasem Rezanejade Bardajee, Zari Hooshyar, and Yousof Pourhasan Department of Chemistry, Payame Noor University, Tehran 19395-4697, Iran Correspondence should be addressed to Ghasem Rezanejade Bardajee, ghrezanejad@ Received 20 July 2011; Revised 29 August 2011; Accepted 4 September 2011 Academic Editor: Jaan Laane Copyright © 2011 Ghasem Rezanejade Bardajee et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. A new fluorescent composite based on CdS quantum dots immobilized on the multidentate biopolymer matrix is prepared through the graft copolymerization of the acrylamide onto kappa-Carrageenan. A variety of techniques like thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR) was used to confirm the structure of the obtained samples. To investigate the spectrofluorometric properties, fluorescence spectroscopy of the obtained quantum dots was studied. 1. Introduction used to prepare water-soluble semiconductor QDs: ligand exchange [15, 16], encapsulation into a water-soluble shell Semiconductor quantum dots (QDs), also called nanocrys- (i.e., the silica or phospholipids) [17, 18], and surface