三氯氢硅和四氯化硅的物化性质（The physicochemical properties of four trichlorosilane and silicon tetrachloride）.docVIP

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三氯氢硅和四氯化硅的物化性质（The physicochemical properties of four trichlorosilane and silicon tetrachloride）.doc

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三氯氢硅和四氯化硅的物化性质（The physicochemical properties of four trichlorosilane and silicon tetrachloride）

三氯氢硅和四氯化硅的物化性质（The physicochemical properties of four trichlorosilane and silicon tetrachloride） The physicochemical properties of four trichlorosilane and silicon tetrachloride SiHCl3 alias name English trichlorosilane 1.? Silicon silicon, chloroform, imitation three chloro silane; Trichlorosilane, Silicochloroform.2. uses silicon materials, epitaxial growth, silicon fluid, silicone oil, chemical vapor deposition, silicone compound manufacture, electron gas. The 3. method (1) at high temperature Si and HCl reaction. (2) four reduction of silicon tetrachloride with hydrogen (catalyst using aluminum containing compounds). 4. physicochemical properties of molecular weight: 135.43 melting point (101.325kPa):-134 (101.325kPa):31.8 C; boiling point C; liquid density (0 C):1350kg/m3; relative density (gas, air =1:4.7); vapor pressure (-16.4 C):13.3kPa;:53.3kPa (14.5 DEG C); ignition temperature of -27.8 DEG C; autoignition temperature: 104.4 degrees flash point: -14; C; explosion limit: 9.8%; toxicity level: 3; flammability level: 4; explosive level: 2 three chlorosilanes under normal temperature and pressure with colorless irritating odor free flowing volatile transparent liquid. Very easy to burn in the air, at -18 DEG C also has the danger of fire, in case of fire is intense burning, burning with a red flame and white smoke, SiO2, HCl and Cl2:SiHCl3+O2 to generate SiO2+HCl+Cl2; can form an explosive mixture of a wide range of concentration and air three chlorosilanes, cause a violent explosion when heated. Its thermal stability than two chlorosilanes, decomposition at 900 DEG C produce toxic fumes chloride (HCl), Cl2 and Si were also produced. In case of moisture of smoke, and the intense reaction water: 2SiHCl3+3H2O, 2O+6HCl; (HSiO) in alkaline solution decomposition hydrogen: SiHCl3+3NaOH+H2O, Si (OH) 4+3NaCl+H2; explosive reaction with oxidant contact. The formation of organic chlorosilane and reaction of acetylene, hydrocarbons and other hydrocarbons: SiHCl3+CH = C