homo-polymerization of α-olefins and co-polymerization of higher α-olefins with ethylene in the presence of cpticl2(oc6h4x-p)mao catalysts (x = ch3, cl)homo-polymerizationα-olefins和与乙烯的共聚高α-olefins cpticl2毛(oc6h4x-p)催化剂(x = ch3,cl).pdfVIP

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homo-polymerization of α-olefins and co-polymerization of higher α-olefins with ethylene in the presence of cpticl2(oc6h4x-p)mao catalysts (x = ch3, cl)homo-polymerizationα-olefins和与乙烯的共聚高α-olefins cpticl2毛(oc6h4x-p)催化剂(x = ch3,cl).pdf

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homo-polymerization of α-olefins and co-polymerization of higher α-olefins with ethylene in the presence of cpticl2(oc6h4x-p)mao catalysts (x = ch3, cl)homo-polymerizationα-olefins和与乙烯的共聚高α-olefins cpticl2毛(oc6h4x-p)催化剂(x = ch3,cl)

Molecules 2005, 10, 659-671 molecules ISSN 1420-3049 Homo-polymerization of α-Olefins and Co-polymerization of Higher α-Olefins with Ethylene in the Presence of CpTiCl (OC H X-p )/MAO Catalysts (X = CH , Cl) 2 6 4 3 W. Skupinski*, K. Nicinski †, D. Jamanek and Z. Wieczorek Industrial Chemistry Research Institute, Department of Engineering Plastics and Special Polymers, Group of Catalytic Polymerization, Rydygiera 8, 01-793 Warsaw, Poland; † e-mail: karol.nicinski@ichp.pl * Author to whom correspondence should be addressed; e-mail: wincenty.skupinski@ichp.pl Received: 05 August 2004 / Accepted: 23 September 2004 / Published: 14 July 2005 Abstract: Cyclopentadienyl-titanium complexes containing –OC H X ligands (X = Cl, 6 4 CH ) activated with methylaluminoxane (MAO) were used in the homo-polymerization 3 of ethylene, propylene, 1-butene, 1-pentene, 1-butene, and 1-hexene, and also in co- polymerization of ethylene with the α-olefins mentioned. The -X substituents exhibit different electron donor-acceptor properties, which is described by Hammett’s factor (σ). The chlorine atom is electron acceptor, while the methyl group is electron donor. These catalysts allow the preparation of polyethylene in a good yield. Propylene in the presence o of t