polystyrene based silver selective electrodes基于聚苯乙烯的选择性银电极.pdfVIP

Sensors 2002, 2, 233-243 sensors ISSN 1424-8220 © 2002 by MDPI /sensors Polystyrene Based Silver Selective Electrodes 1,* 2 1 1 Vinod Kumar Gupta , Milan M. Antonijevic , Sudeshna Chandra and Shiva Agarwal 1 Department of Chemistry, Indian Institute of Technology Roorkee (formerly University of Roorkee), Roorkee- 247667 (India). Tel: 0091-1332-85801. Fax: 0091-1332-73650. 2 Department of Chemistry and Chemical Technology, Technical Faculty Bor, University of Belgrade, P.O.Box 50, 19210 Bor, Serbia, Yugoslavia * Author to whom correspondence should be addressed. E-mail: vinodfcy@iitr.ernet.in Received: 2 June 2002 / Accepted: 18 June 2002 / Published: 24 June 2002 Abstract: Silver(I) selective sensors have been fabricated from polystyrene matrix membranes containing macrocycle, Me (14) diene.2HClO as ionophore. Best performance 6 4 was exhibited by the membrane having a composition macrocycle : Polystyrene in the ratio -6 -1 15:1. This membrane worked well over a wide concentration range 5.0×10 –1.0×10 M of Ag+ with a near-Nernstian slope of 53.0 ± 1.0 mV per decade of Ag+ activity. The response time of the sensor is 15 s and the membrane