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polysilane dendrimers聚合物基
Polymers 2012, 4, 408-447; doi:10.3390/polym4010408
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Review
Polysilane Dendrimers
Clemens Krempner
Department of Chemistry Biochemistry, Texas Tech University, Memorial Dr. Boston, Lubbock,
TX 79409, USA; E-Mail: clemens.krempner@; Tel.: +1-806-742-3064; Fax: +1-806-742-1289
Received: 15 December 2011; in revised form: 21 January 2012 / Accepted: 29 January 2012 /
Published: 9 February 2012
Abstract: The synthesis, structure and electronic properties of polysilane dendrimers, a
relatively new class of highly branched and silicon-rich molecular architectures is
reviewed. After a detailed discussion of main synthetic strategies to well-defined
single-core and double-core polysilane dendrimers, important structural and conformational
features determined by single crystal X-ray crystallography and 29Si-NMR spectroscopy
are presented. The last part highlights the most interesting photochemical properties of
polysilane dendrimers such as UV absorption and emission behavior, which are compared
with those of linear and branched polysilanes.
Keywords: polysilane; dendrimer; oligosilane; 29Si-NMR spectroscopy; UV spectroscopy;
conformation; emission
1. Introduction
The last three decades have seen intense research in the field of poly- and oligosilanes,
organosilicon compounds that are composed of one or more silicon-silicon bonds. Interest in this cla
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