原创力文档radical-scavenging activity and cytotoxicity of p-methoxyphenol and p-cresol dimers自由基清除活性和细胞毒性p-methoxyphenol p-cresol二聚体.pdfVIP
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radical-scavenging activity and cytotoxicity of p-methoxyphenol and p-cresol dimers自由基清除活性和细胞毒性p-methoxyphenol p-cresol二聚体
Molecules 2010, 15, 1103-1112; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Radical-Scavenging Activity and Cytotoxicity of
p -Methoxyphenol and p -Cresol Dimers
1 2 2 2 3
Yoshinori Kadoma , Yukio Murakami , Takako Ogiwara , Mamoru Machino , Ichiro Yokoe
and Seiichiro Fujisawa 2,*
1 Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, Kanda-
surugadai, Chiyoda-ku, Tokyo 101-0062 Japan; E-Mail: y-kadoma.fm@tmd.ac.jp (Y.K.)
2 Meikai University School of Dentistry, Sakado, Saitama 350-0283, Japan;
E-Mails: ymura@dent.meikai.ac.jp (Y.M.); a-hirata@dent.meikai.ac.jp (T.O.);
machino@dent.meikai.ac.jp (M.M.)
3 Faculty of Pharmaceutical Sciences, Josai University, Saitama 350-0295 Japan;
E- Mail: yokoe@josai.ac.jp (I.Y.)
* Author to whom correspondence should be addressed; E-Mail: fujisawa33@;
Tel.: +81-049-285-5511; Fax: (+81)-49-287-6657.
Received: 4 December 2009; in revised form: 21 February 2010 / Accepted: 21 February 2010 /
Published: 26 February 2010
Abstract: Compounds with two phenolic OH groups like curcumin possess efficient
antioxidant and anti-inflammatory activity. We synthesized p- cresol dimer (2,2-dihydroxy-
5,5-dimethylbiphenol, 2a) and p- methoxyphenol dimer (2,2-dihydroxy-5,5-
dimethoxybiphenol, 2b) by ortho-ortho coupling reactions of the par
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