ring opening metathesis polymerization of norbornene and derivatives by the triply bonded ditungsten complex na[w2(μ-cl)3cl4(thf)2]·(thf)3开环复分解聚合norbornene和衍生品的三重保税ditungsten复杂na(w2(μ-cl)3 cl4(四氢呋喃)2]·(四氢呋喃)3.pdfVIP
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ring opening metathesis polymerization of norbornene and derivatives by the triply bonded ditungsten complex na[w2(μ-cl)3cl4(thf)2]·(thf)3开环复分解聚合norbornene和衍生品的三重保税ditungsten复杂na(w2(μ-cl)3 cl4(四氢呋喃)2]·(四氢呋喃)3
Polymers 2012, 4, 1657-1673; doi:10.3390/polym4041657
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Article
Ring Opening Metathesis Polymerization of Norbornene and
Derivatives by the Triply Bonded Ditungsten Complex
Na[W (µ -Cl) Cl (THF) ]·(THF)
2 3 4 2 3
Dedicated to my research colleagues at Sir G. Wilkinson’s Laboratory (1972–1980).
1 1 1 1
Georgios Floros , Nikolaos Saragas , Patrina Paraskevopoulou , Nikolaos Psaroudakis ,
Spyros Koinis 1, Marinos Pitsikalis 2, Nikos Hadjichristidis 2 and Konstantinos Mertis 1,*
1 Department of Inorganic Chemistry, Faculty of Chemistry, University of Athens,
Panepistimioupoli Zographou, Athens 15771, Greece; E-Mails: geofloros@chem.uoa.gr (G.F.);
nsaragas@sch.gr (N.S.); paraskevopoulou@chem.uoa.gr (P.P.); psaroudakis@chem.uoa.gr (N.P.);
koinis@chem.uoa.gr (S.K.)
2 Department of Industrial Chemistry, Faculty of Chemistry, University of Athens,
Panepistimioupoli Zographou, Athens 15771, Greece; E-Mails: pitsikalis@chem.uoa.gr (M.P.);
hadjichristidis@chem.uoa.gr (N.H.)
* Author to whom correspondence should be addressed; E-Mail: cmertis@chem.uoa.gr (K.M.);
Tel.: +30-210-727-4332; Fax: +30-210-727-4782.
Received: 7 October 2012; in revised form: 10 November 2012 / Accepted: 14 November 2012 /
Published: 21 November 2012
Abstract: In this study, the reactions of the bimetallic compound
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