the effect of uv-irradiation (under short-circuit condition) on dye-sensitized solar cells sensitized with a ru-complex dye functionalized with a (diphenylamino)styryl-thiophen group英文论文.pdfVIP

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the effect of uv-irradiation (under short-circuit condition) on dye-sensitized solar cells sensitized with a ru-complex dye functionalized with a (diphenylamino)styryl-thiophen group英文论文.pdf

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the effect of uv-irradiation (under short-circuit condition) on dye-sensitized solar cells sensitized with a ru-complex dye functionalized with a (diphenylamino)styryl-thiophen group英文论文

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2009, Article ID 471828, 9 pages doi:10.1155/2009/471828 Research Article The Effect of UV-Irradiation (under Short-Circuit Condition) on Dye-Sensitized Solar Cells Sensitized with a Ru-Complex Dye Functionalized with a (diphenylamino)Styryl-Thiophen Group Kazuteru Nonomura,1 Yunhua Xu,1 Tannia Marinado,1 Daniel P. Hagberg,1 Rong Zhang,2 Gerrit Boschloo,1, 3 Licheng Sun,1 and Anders Hagfeldt1, 3 1 Department of Chemistry, Center of Molecular Devices, Royal Institute of Technology (KTH), Teknikringen 30, 100 44 Stockholm, Sweden 2 State Key Laboratory of Fine Chemicals, DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian University of Technology (DUT), Dalian 116012, China 3 Department of Physical and Analytical Chemistry, Uppsala University, Box 259, 751 05 Uppsala, Sweden Correspondence should be addressed to Kazuteru Nonomura, kazuteru@kth.se Received 22 January 2009; Accepted 18 May 2009 Recommended by Mohamed Sabry Abdel-Mottaleb A new ruthenium complex, cis-di(thiocyanato)(2,2 -bipyridine-4,4 -dicarboxylic acid)(4,4 -bis(2-(5-(2-(4-diphenylamino- phenyl)ethenyl)-thiophen-2-yl)ethenyl)-2,2 -bipyridine)ruthenium(II) (named E322) has been synthesized for use in dye- sensitized solar cells (DSCs). Higher extinction coeﬃcient and a broader absorption compared to the standard Ru-dye, N719, were aimed. DSCs were fabricated with E322, and the eﬃciency was 0.12% initially. (4.06% for N719, as reference). The eﬃciency was enhanced to 1.83% by exposing the cell under simulated sunlight containing UV-irradiation at short-circuit condition. The