the short series of the oxygen-poor lanthanide oxide selenides m10ose14 with m = la–nd的短系列缺氧氧化镧系元素硒化物与m = la-nd m10ose14.pdfVIP
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the short series of the oxygen-poor lanthanide oxide selenides m10ose14 with m = la–nd的短系列缺氧氧化镧系元素硒化物与m = la-nd m10ose14
Crystals 2012, 2, 1136-1145; doi:10.3390/cryst2031136
OPEN ACCESS
crystals
ISSN 2073-4352
/journal/crystals
Article
The Short Series of the Oxygen-Poor Lanthanide Oxide
Selenides M10OSe14 with M = La–Nd
Frank A. Weber, Christian M. Schurz, Susanne Frunder, Charlotte F. Kuhn
and Thomas Schleid *
Institute for Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, Stuttgart D-70569,
Germany; E-Mails: f.a.weber@freenet.de (F.A.W.); schurz@iac.uni-stuttgart.de (C.M.S.);
susanne.wunderle@uni-hohenheim.de (S.F.); kuhn@iac.uni-stuttgart.de (C.F.K.)
* Authors to whom correspondence should be addressed; E-Mail: schleid@iac.uni-stuttgart.de;
Tel.: +49-711-6856-4240; Fax: +49-711-6856-4241.
Received: 6 June 2012; in revised form: 6 July 2012 / Accepted: 17 July 2012 /
Published: 16 August 2012
Abstract: Single crystals and phase pure samples of oxygen-poor ternary lanthanide
oxide selenides with the composition M OSe (M = La–Nd; tetragonal, I4 /acd;
10 14 1
a = 1592.0–1559.8 pm, c = 2106.5–2062.9 pm) could be obtained by reacting the
corresponding metals, selenium and selenium dioxide as oxygen source. Their crystal
structures are isotypic with Pr OS and thus contain isolated [OM ]10+ tetrahedra
10 14 4
(d(O2––M3+) = 243
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