近红外光谱法研究升温导致的尼龙1010结晶区域的变化ANear.PDF

2008 年第 66 卷 化 学 学 报 Vol. 66, 2008 第 16 期, 1903～1908 ACTA CHIMICA SINICA No. 16, 1903～1908 ·研究论文· 近红外光谱法研究升温导致的尼龙 1010 结晶区域的变化 徐 艳 武培怡* (复旦大学高分子科学系 聚合物分子工程教育部重点实验室 上海 200433) 摘要 采用近红外光谱技术和二维相关分析法研究尼龙 1010 膜在升温过程中的结构变化. 为了排除非晶区域酰胺基 团的影响, 事先对尼龙 1010 的样品膜进行了氘代, 并测量了其最终氘代率. 结果证明, 尼龙 1010 的结晶区域在升温过 程中被逐渐破坏, 首先是其主链碳氢结构发生调整, 进一步影响到结合酰胺, 导致氢键作用减弱并最后生成自由胺基. 关键词 尼龙 1010; 氘代; 近红外光 ; 二维相关分析 A Near Infrared Spectroscopic Study of Temperature-induced Changes of Crystalline Domains in a Nylon 1010 Sample XU, Yan WU, Pei-Yi* (Key Laboratory of Molecular Engineering of Polymers (Ministry of Education), Department of Macromolecular Science, Fudan University, Shanghai 200433) Abstract Near infrared (NIR) spectroscopy in combination with two-dimensional correlation analysis were applied to investigate the heating process of a deuterated nylon 1010 film. To suppress the interference of amide groups in the amorphous phase, the film was placed in heavy water for 4 weeks for deuteration and the deuteration rate was determined. The results indicated that the crystalline domains of nylon 1010 were gradually destroyed upon heating. During the heating process, the methylene groups in the backbone changed earlier than the dissociation process of the intermolecular hydrogen bonding of the amide groups. Keywords nylon 1010; deuteration; near infrared spectroscopy; two-dimensional correlation analysis 尼龙 1010 是一种常见的工程塑料, 其结构式如图 1 近红外光谱(Near Infrar