第二章 自由基聚合（The second chapter is free radical polymerization）.docVIP

第二章 自由基聚合（The second chapter is free radical polymerization） The second chapter is free radical polymerization 1. the kinetics of styrene polymerization at 60 DEG C was studied using peroxide two benzoyl as initiator. The data are as follows: (1) the density of styrene at 60 DEG C is 0.887g/mL (2) the dosage of initiator was 0.109% of single weight (3) Rp = 0.255 * 10-4, mol/, L, s (4) polymerization degree = 2460 (5) f = 0.80 (6) radical life t = 0.82s Try KD, KP, KT, establish the order of magnitude of three constants, compare the size of [M] and [M [], compare the size of Ri, Rp, Rt. All for coupling termination, a = 0.5 Solution: 1L styrene: The concentration of styrene monomer is [M] = 0.887 * 103/104 = 8.53mol/L (104 is styrene molecular weight) The initiator concentration is [I]= 0.887 * 103 * 0.00109/242=4.0 * 10-3mol/L (242 is BPO molecular weight) Substitution data Xie jie: Kd = 3.23 * 10-6 S-1 10-4~10-6 KP = 1.76 * 102 L/mol s 102~104 KT = 3.59 * 107 L/mol s 106~108 [M =] = Rp/, kp[M]=0.255 * 10-4/ (1.76 * 102 * 8.53) = 1.70 * 10-8mol/L And [M]=8.53mol/L is visible, [M][M [] Ri=2fkd[I]=2 x 0.80 x 3.23 x 10-6 x 4 x 10-3 = 2.07 * 10-8mol/L * s Rt=2kt[M *]2=2 * 3.59 * 107 x (1.70 * 10-8) 2 = 2.07 * 10-8mol/L * s The known Rp=2.55 x 10-5mol/L = s, visible RpRi = Rt 2. polymerization of styrene was studied at 60 DEG C with two tert butyl peroxide as initiator. The initial rate of styrene solution concentration (1.0mol/L), peroxide (0.01mol/L), initiation and polymerization was 4 x 10-11 and 1.5 * 10-7mol/ (L = s), respectively. Calculation (F, KD), initial polymerization degree, initial kinetic chain length. In calculation, the following data and conditions are used: CM=8.0 * 10-5, CI = 3.2 * 10-4, CS = 2.3 * 10-6, 60 DEG C, styrene density is 0.887g/ml, benzene density is 0.839g/ml, styrene styrene system is ideal solution. Solution 1: Ri = 2F, KD, [I], substituting data 4 x 10-11 = 2F, KD * 0.01 * f KD * 10-9 = 2 Rp=kp (f kd/kt) 1/2[I]1/2[M] dreams By substi