二甲基二烯丙基氯化铵的辐射聚合和性质研究-上海有机化学研究所.PDFVIP

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 8 期 , 1507～1512 ACTA CHIMICA SINICA No. 8 , 1507 ～1512 二甲基二烯丙基氯化铵的辐射聚合和性质研究 任　静　　张　扬　　伊　敏　　哈鸿飞 (北京大学化学与分子工程学院 　北京 100871) 摘要 　对二甲基二烯丙基氯化铵进行了辐射聚合 ,得到线型聚合物和交联的水凝胶 ,实验测定了线型聚合的转 化率与剂量和水凝胶的凝胶分数、平衡溶胀与剂量的关系. 结果表明聚二甲基二烯丙基氯化铵水凝胶的凝胶含 量与剂量的关系符合 CharlesbyPinner 公式 ,外推 S + S 12 = 2 求得凝胶剂量 Dg ,从而求出 G( x ) 等值 ;并首次利 用二甲基二烯丙基氯化铵及其聚合物稀水溶液的电导率与浓度的线性关系 ,发展了一种对电解质的辐射聚合 反应转化率的电导测定法. 关键词 　二甲基二烯丙基氯化铵 ,水凝胶 ,辐射聚合 , 电导率,交联度 ,凝胶剂量 Radiation Synthesis and Characteristic of Diallyldimethylammonium Chloride REN , Jing 　　ZHANG, Yang 　　YI , Min 　　HA , HongFei ( ) College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 Abstract 　Linear homopolymers and hydrogels of diallyldimethylammonium chloride (DADMAC) were synthesized by gamma irradiation. The relationships between conversion , molecular weight and dose of the polymerization were studied. The results show that the relationship between the gel fraction and dose is in accord with CharlesbyPinner Equation. From the equation , ( Dg ) , G ( x ) , p , q and M c were calculated. According to the linear relationship between the conductivity and the concentration of DADMAC monomer or homopolymer aqueous solution , the electrical conductivity was first used to detect the conversion of the radiation polymerization. Keywords