生物农药印楝素的热稳定性研究-河南农业科学.pdfVIP

DOI :10.15933/j.cnki .1004 -3268.2004.05.011 2004 年第5 期 1,2 1 ＊ 3 王秋芬 ,宋湛谦 , 闫新华 (1 , 210042; 2 ;3 ) :研究了水分、黄曲霉、溶剂、乳化剂、稳定剂等因素对印楝素热稳定性的影响, 结果表明: 除去水分、黄曲霉 的固体印楝素稳定性有明显改善,印楝素在各种溶剂中的稳定性为:二甲 苯-乙腈(2 ∶1)≈二甲苯-乙酸乙酯(2 ∶1)二甲亚砜乙腈乙酸乙酯丙酮甲醇≈乙 醇;各种乳化剂的存在加速印楝素的分解,其中热分解速度:十二烷基苯磺酸钠吐温-80 CH100吐温-20 ≈CH400 ;加入热稳定剂 能明显改善印楝素的稳定效果, 其中环氧化豆油的 稳定效果较好。 :生物农药;印楝素;热稳定性;热稳定剂 :S476 　　:A 　　:1004-3268(2004)05-0037-04 Studies on Thermal Stability of Biolo ic Pesticide Azadirachtin 1,2 1 3 WANG Qiu-fen ,SONG Zhan-qian ,YAN Xin-hua (1 Institute of Chemical Industry of Forest Products, CAF, Nanjin 210042, China; 2 Colle e of Chemistry and Chemical En ineerin , Jinan University; 3 Shandon Huayan T echnolo y Incorporated Company ) Abstract:Effect of moisture,aflatoxin, solvents, emulsifier and thermal stabilizers on thermal sta- bility of azadirachtin w as investi ated .It w as found that thermal stability of solid azadirachtin has been obviously improved by removal of moisture and aflatoxin .The order of azadirachtin thermal stability in different solvents was as follow :Xylene-acetonitrile (2:1)≈xylene-ethyl acetate (2 ∶ 1)DMSO acetonitrileethyl acetateacetone methanol ≈ethanol.All kinds of emulsi- fier enhanced the rate of thermal de radation of azadirachtin in solution.The rate of thermal de radation w as as:LAS Tew een-80 CH100Tew een-20 ≈CH400 .The thermal stability of azadirachtin w as enhanced by addition thermal stabilizers in solution .It w as found that epox - ideized soybean oil w as the best thermal stabilizers. Key words:Biolo ic pesticide;Azadirachtin;Thermal stability ;Thermal stab