一个改进的制冷剂表面张力与黏度互推模型.pdfVIP

一个改进的制冷剂表面张力与黏度互推模 型 摘 要：表面张力和黏度是流体重要的热物理性质，本文在前人研究的基础上，提出了一个 进的针对制 冷剂表面张力和黏度的互推模型。利用32种制冷剂(R13、R14、R32、R23、R41、R123、R125、R134a、R1 41b、R142b、R152a、R218、R143a、R227ea、RC318、R11 、R12、R21、R22、R113、R114、R115、R116、R1 24、R236ea、R236fa、R245ca、R245fa、R1234yf、R1234ze(E)、R161、R365mfc)饱和态的表面张力和黏度 数据对模型进行了验证。结果表明，模型很好的描述了从三相点附近到近临界点的表面张力和黏度的 关系。 关键词：表面张力；黏度；制冷剂 An improved Correlation Between Surface Tension and Viscosity for Refrigerants YUE Hong-Ya, MA Qian, WANG Xiao-Po*, LIU Zhi-Gang (Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi’an Jiaotong University, Xi’an 710049, China) Abstract: Surface tension and viscosity are two important thermophysical properties of fluids. In this work, based on previous investigations, an improved correlation between surface tension and viscosity for saturated refrigerants were established. Surface tension and viscosity values of 32 refrigerants (R13、R14、R32、R23 、R41、R123、R125、R134a、R141b、R142b、R152a、R218、R143a、R227ea、RC318 、R11、R12、R21 、R22、R113、R114、R115、R116、R124、R236ea、R236fa 、R245ca、R245fa、R1234yf、R 1234ze、R161、R365mfc) are used to verify the proposed model. The result shows that the improved correlation can describe the relationship between surface tension and viscosity very well. Key word: Surface tension; viscosity; refrigerant 0. 前言 基金项目：国家自然科学基金资助项目（No. 流体的表面张力和黏度是两种基本的热物理性质。准确的表面张力和黏 度数据对于工业生产的优化设计、流程监控等十分重要。另一方面，流体的表 面张力和黏度都与分子间的势能有关，因此二者之间应该存在一定的内在联 系。尽管目前国际上关于表面张力和黏度之间内在联系机理还不明确，但从 宏观角度而言，国内外学者已 建立了二者一定的互推关联式。 最早展开表面张力和黏度之间关系研究的是Silverman和Roseveare，这两 [1] 位学者在1932年提出了一个经验型的表面张力和黏度关联式 ，但其应用的 范围非常有限。随后，许多学者都对此展开了研究，主要包括Pelofsky[2]、Scho nhorn[3]、Queimada[4]、Ghatee [5]、Tian等[6- 8] 。这些学者提出的表面张力和黏度的关联式将在后续给出。本文在前人工作 的基础上，将 进型的VFT黏度方程（Vogel-Fulcher- Tammann方程）与表面张力